The structural and multiferroic properties of Bi(1−x)Ce x Fe(1−x)(Mg0.5Ti0.5) x O3 thin films

作者: Xiaohang Wu , Yanchun Xie , Shenghong Yang , Yueli Zhang

DOI: 10.1007/S10854-017-7608-9

关键词:

摘要: Bi(1−x)Ce x Fe(1−x)(Mg0.5Ti0.5) O3 (x = 0, 0.05, 0.10, 0.20, 0.25) thin films were synthesized by a sol–gel method. The structural, electrical and magnetic properties of have been investigated. BiFeO3 film possessed perovskite-type rhombohedral structure with space group R3c, the average grain size decreased as concentration Ce, Mg Ti co-doping increased. leakage current densities ions exhibited significant reduction compared that film. Compared density (4.19 × 10−4 A/cm2), Bi0.80Ce0.20Fe0.80Mg0.10Ti0.10O3 was reduced about four orders magnitude (1.05 × 10−8 A/cm2) under electric field 300 kV/cm. Well-defined ferroelectric loops obtained polarization increased increase co-doping. remanent (2P r  ~34.9 μC/cm2) approximately times larger than pure  ~7.8 μC/cm2) applied magnetization 10 kOe increasing improvement behaviors for observed significantly, cooperating enhanced ferroelectricity which indicated will be promising materials in application to magnetoelectric devices.

参考文章(35)
Vivek Verma, Anu Beniwal, Anil Ohlan, Rahul Tripathi, None, Structural, magnetic and ferroelectric properties of Pr doped multiferroics bismuth ferrites Journal of Magnetism and Magnetic Materials. ,vol. 394, pp. 385- 390 ,(2015) , 10.1016/J.JMMM.2015.06.067
J. W. Kim, C. M. Raghavan, S. S. Kim, Structural and electrical properties of 0.7BiFeO3–0.3CaTiO3 solid solution thin films deposited from solutions Journal of Sol-Gel Science and Technology. ,vol. 76, pp. 693- 698 ,(2015) , 10.1007/S10971-015-3822-1
K. G. Yang, Y. L. Zhang, S. H. Yang, B. Wang, Structural, electrical, and magnetic properties of multiferroic Bi1−xLaxFe1−yCoyO3 thin films Journal of Applied Physics. ,vol. 107, pp. 124109- ,(2010) , 10.1063/1.3437232
Dong Hong, Shengwen Yu, Jinrong Cheng, Sm–Ti co-substituted BiFeO3 thin films prepared by sol–gel technique Current Applied Physics. ,vol. 11, ,(2011) , 10.1016/J.CAP.2011.01.029
P. Mandal, M. J. Pitcher, J. Alaria, H. Niu, P. Borisov, P. Stamenov, J. B. Claridge, M. J. Rosseinsky, Designing switchable polarization and magnetization at room temperature in an oxide Nature. ,vol. 525, pp. 363- 366 ,(2015) , 10.1038/NATURE14881
N. M. Murari, R. Thomas, R. E. Melgarejo, S. P. Pavunny, R. S. Katiyar, Structural, electrical, and magnetic properties of chemical solution deposited BiFe1−xTixO3 and BiFe0.9Ti0.05Co0.05O3 thin films Journal of Applied Physics. ,vol. 106, pp. 014103- ,(2009) , 10.1063/1.3158556
J. Zeng, Z. H. Tang, M. H. Tang, D. L. Xu, Y. G. Xiao, B. W. Zeng, L. Q. Li, Y. C. Zhou, Enhanced ferroelectric, dielectric and leakage properties in Ce and Ti co-doping BiFeO3 thin films Journal of Sol-Gel Science and Technology. ,vol. 72, pp. 587- 592 ,(2014) , 10.1007/S10971-014-3481-7
Jun Liu, Meiya Li, Ling Pei, Benfang Yu, Dongyun Guo, Xingzhong Zhao, Effect of Ce doping on the microstructure and electrical properties of BiFeO3 thin films prepared by chemical solution deposition Journal of Physics D. ,vol. 42, pp. 115409- ,(2009) , 10.1088/0022-3727/42/11/115409
Jun Liu, Meiya Li, Ling Pei, Jing Wang, Benfang Yu, Xiao Wang, Xingzhong Zhao, Structural and multiferroic properties of the Ce-doped BiFeO3 thin films Journal of Alloys and Compounds. ,vol. 493, pp. 544- 548 ,(2010) , 10.1016/J.JALLCOM.2009.12.152
Wei Cai, Chunlin Fu, Rongli Gao, Weihai Jiang, Xiaoling Deng, Gang Chen, Photovoltaic enhancement based on improvement of ferroelectric property and band gap in Ti-doped bismuth ferrite thin films Journal of Alloys and Compounds. ,vol. 617, pp. 240- 246 ,(2014) , 10.1016/J.JALLCOM.2014.08.011