Surfactant free synthesis of CdS nanospheres, microstructural analysis, chemical bonding, optical properties and photocatalytic activities
作者： R. Sankar Ganesh , Sanjeev K. Sharma , E. Durgadevi , M. Navaneethan , H.S. Binitha
DOI: 10.1016/J.SPMI.2017.02.029
关键词:
摘要: Abstract The surfactant free cadmium sulfide (CdS) nanospheres were synthesized by the chemical method in a single step. uniform shape of CdS spheres was controlled variation concentration thioacetamide (C2H5NS). cubic phase nanopowder determined from XRD analysis, which closely matched to standard card. spherical grains powder confirmed microstructural analysis. (TAA) played vital role formation nanospheres. bandgap decreased 2.44 2.22 eV as mole C2H5NS increased 0.05 M 2.0 M. FTIR spectra presence stretching bond Cd S. dominant PL peak purely and uniformed observed at 528 nm due S vacancies or surface defects. prepared photocatalyst demonstrated superior visible light photocatalytic degradation methylene blue (MB). highest (96%) MB achieved within 180 min. Therefore, grown step has remarkable enhancement pollutants under irradiation light.
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Xiujuan Zhuang, Qinglin Zhang, Qiang Wan, Huayong Pan, Xiaoli Zhu, Anlian Pan, Quanming Hao, Jingyou Xu, Template-free synthesis and photocatalytic activity of CdS nanorings Materials Letters. ,vol. 100, pp. 141- 144 ,(2013) , 10.1016/J.MATLET.2013.02.091
Jing Chen, Bin-Bin Ding, Tai-Ya Wang, Fang Li, Yong Zhang, Yu-Ling Zhao, Hai-Sheng Qian, Facile synthesis of uniform ZnxCd1−xS alloyed hollow nanospheres for improved photocatalytic activities Journal of Materials Science: Materials in Electronics. ,vol. 25, pp. 4103- 4109 ,(2014) , 10.1007/S10854-014-2135-4
Hyeokjin Lee, Heesun Yang, Paul H. Holloway, Functionalized CdS nanospheres and nanorods Physica B-condensed Matter. ,vol. 404, pp. 4364- 4369 ,(2009) , 10.1016/J.PHYSB.2009.09.020
R. Rameshbabu, R. Ramesh, S. Kanagesan, A. Karthigeyan, S. Ponnusamy, Effect of TEA on the structural and magnetic properties of ferromagnetic ZnFe2O4 nanoparticles Journal of Materials Science: Materials in Electronics. ,vol. 26, pp. 547- 553 ,(2015) , 10.1007/S10854-014-2433-X
Zhihui Dai, Hongyan Bai, Mei Hong, Yinyan Zhu, Jianchun Bao, Jian Shen, A novel nitrite biosensor based on the direct electron transfer of hemoglobin immobilized on CdS hollow nanospheres. Biosensors and Bioelectronics. ,vol. 23, pp. 1869- 1873 ,(2008) , 10.1016/J.BIOS.2008.03.002
Nayereh Soltani, Elias Saion, W. Mahmood Mat Yunus, Manizheh Navasery, Ghazaleh Bahmanrokh, Maryam Erfani, Mohammad Reza Zare, Elham Gharibshahi, Photocatalytic degradation of methylene blue under visible light using PVP-capped ZnS and CdS nanoparticles Solar Energy. ,vol. 97, pp. 147- 154 ,(2013) , 10.1016/J.SOLENER.2013.08.023
Eveliina Repo, Selvaraj Rengaraj, Susanna Pulkka, Emmanuelle Castangnoli, Sami Suihkonen, Markku Sopanen, Mika Sillanpää, Photocatalytic degradation of dyes by CdS microspheres under near UV and blue LED radiation Separation and Purification Technology. ,vol. 120, pp. 206- 214 ,(2013) , 10.1016/J.SEPPUR.2013.10.008
Chonghai Deng, Xiaobo Tian, Facile microwave-assisted aqueous synthesis of CdS nanocrystals with their photocatalytic activities under visible lighting Materials Research Bulletin. ,vol. 48, pp. 4344- 4350 ,(2013) , 10.1016/J.MATERRESBULL.2013.07.019
Zhou Yu, Bosi Yin, Fengyu Qu, Xiang Wu, Synthesis of self-assembled CdS nanospheres and their photocatalytic activities by photodegradation of organic dye molecules Chemical Engineering Journal. ,vol. 258, pp. 203- 209 ,(2014) , 10.1016/J.CEJ.2014.07.041
Nan Ma, Jun Yang, Kelly M. Stewart, Shana O. Kelley, DNA-passivated CdS nanocrystals: luminescence, bioimaging, and toxicity profiles. Langmuir. ,vol. 23, pp. 12783- 12787 ,(2007) , 10.1021/LA7017727