Generation of nitrogen-doped photoluminescent carbonaceous nanodots via the hydrothermal treatment of fish scales for the detection of hypochlorite

作者: Guoqin Wu , Miao Feng , Hongbing Zhan

DOI: 10.1039/C5RA04989J

关键词:

摘要: Preparing nitrogen-doped (N-doped) photoluminescent carbonaceous nanodots (C-dots) from the recycling/utilisation of nitrogen-rich waste has received considerable research interest. In this work, by using fish scales, an abundant food industry waste, as a starting material, we have developed green, cheap and convenient approach for preparation N-doped C-dots, which represents great potential large-scale production. The as-synthesized C-dots are highly soluble, regularly sphere shaped homogeneously sized with average diameter 2 nm. X-ray photoelectron spectroscopy results demonstrate that nitrogen content can reach 14.6%, is higher than most reported previously. present narrow photoluminescence emission band (400–490 nm) high quantum yield up to 17%, owing fluorescence enhancement effect doping. Besides, their be sensitively quenched addition hypochlorite (ClO−), making them promising sensing platform ClO−.

参考文章(38)
Jiaojiao Zhou, Zonghai Sheng, Heyou Han, Mingqiang Zou, Chenxu Li, Facile synthesis of fluorescent carbon dots using watermelon peel as a carbon source Materials Letters. ,vol. 66, pp. 222- 224 ,(2012) , 10.1016/J.MATLET.2011.08.081
Haimin Zhang, Yibing Li, Xiaolu Liu, Porun Liu, Yun Wang, Taicheng An, Huagui Yang, Dengwei Jing, Huijun Zhao, Determination of Iodide via Direct Fluorescence Quenching at Nitrogen-Doped Carbon Quantum Dot Fluorophores Environmental Science & Technology Letters. ,vol. 1, pp. 87- 91 ,(2014) , 10.1021/EZ400137J
Wenbo Lu, Xiaoyun Qin, Sen Liu, Guohui Chang, Yingwei Zhang, Yonglan Luo, Abdullah M Asiri, Abdulrahman O Al-Youbi, Xuping Sun, None, Economical, Green Synthesis of Fluorescent Carbon Nanoparticles and Their Use as Probes for Sensitive and Selective Detection of Mercury(II) Ions Analytical Chemistry. ,vol. 84, pp. 5351- 5357 ,(2012) , 10.1021/AC3007939
Tae-Il Kim, Seonhwa Park, Yongdoo Choi, Youngmi Kim, A BODIPY‐Based Probe for the Selective Detection of Hypochlorous Acid in Living Cells Chemistry-an Asian Journal. ,vol. 6, pp. 1358- 1361 ,(2011) , 10.1002/ASIA.201100025
Qinghua Liang, Wangjing Ma, Yao Shi, Zhi Li, Xinming Yang, Easy synthesis of highly fluorescent carbon quantum dots from gelatin and their luminescent properties and applications Carbon. ,vol. 60, pp. 421- 428 ,(2013) , 10.1016/J.CARBON.2013.04.055
Yunfei Sha, Jiaying Lou, Shizhe Bai, Da Wu, Baizhan Liu, Yun Ling, Hydrothermal synthesis of nitrogen-containing carbon nanodots as the high-efficient sensor for copper(II) ions Materials Research Bulletin. ,vol. 48, pp. 1728- 1731 ,(2013) , 10.1016/J.MATERRESBULL.2012.12.010
So Young Park, Hyun Uk Lee, Eun Sik Park, Soon Chang Lee, Jae-Won Lee, Soon Woo Jeong, Chi Hyun Kim, Young-Chul Lee, Yun Suk Huh, Jouhahn Lee, Photoluminescent green carbon nanodots from food-waste-derived sources: large-scale synthesis, properties, and biomedical applications. ACS Applied Materials & Interfaces. ,vol. 6, pp. 3365- 3370 ,(2014) , 10.1021/AM500159P
Baocun Zhu, Yingheng Xu, Weiqian Liu, Changxiang Shao, Huifang Wu, Houlin Jiang, Bin Du, Xiaoling Zhang, A highly selective colorimetric probe for fast and sensitive detection of hypochlorite in absolute aqueous solution Sensors and Actuators B-chemical. ,vol. 191, pp. 473- 478 ,(2014) , 10.1016/J.SNB.2013.10.057
Weili Wei, Can Xu, Li Wu, Jiasi Wang, Jinsong Ren, Xiaogang Qu, Non-Enzymatic-Browning-Reaction: A Versatile Route for Production of Nitrogen-Doped Carbon Dots with Tunable Multicolor Luminescent Display Scientific Reports. ,vol. 4, pp. 3564- 3564 ,(2015) , 10.1038/SREP03564
Pin-Che Hsu, Zih-Yu Shih, Chia-Hsin Lee, Huan-Tsung Chang, Synthesis and analytical applications of photoluminescent carbon nanodots Green Chemistry. ,vol. 14, pp. 917- 920 ,(2012) , 10.1039/C2GC16451E