Effect of potassium content on electrostrictive properties of Na0.5Bi0.5TiO3-based relaxor ferroelectric thin films with morphotropic phase boundary

作者: X.J. Zheng , J.Y. Liu , J.F. Peng , X. Liu , Y.Q. Gong

DOI: 10.1016/J.TSF.2013.09.017

关键词:

摘要: Abstract (1 − x)Na0.5Bi0.5TiO3–xK0.5Bi0.5TiO3 (NBT–KBT100x) (x = 0.13, 0.15, 0.18, 0.20, 0.25) thin films were prepared by metal–organic decomposition, and the crystalline structures, surface morphologies, leakage current densities dielectric, piezoelectric, ferroelectric properties investigated X-ray diffractometer, scanning electron microscopy, semiconductor characterization system, probe tester, respectively. The electrostrictive equation in phenomenological theory is used to model piezoelectric electrostriction behaviors of relaxor films, coefficient couples effective with polarization relative permittivity. strains are larger than for NBT–KBT100x coefficients at ranges 0.019–0.025 m4/C2 0.12%–0.26%, NBT–KBT15 film largest strain, it attributed appropriate potassium content near morphotropic phase boundary equivalent energy coexistence. results indicate that NBT-based high a promising candidate application electromechanical devices.

参考文章(33)
D. Y. Wang, D. M. Lin, K. S. Wong, K. W. Kwok, J. Y. Dai, H. L. W. Chan, Piezoresponse and ferroelectric properties of lead-free [Bi0.5(Na0.7K0.2Li0.1)0.5]TiO3 thin films by pulsed laser deposition Applied Physics Letters. ,vol. 92, pp. 222909- ,(2008) , 10.1063/1.2938364
J. P. MERCURIO, P. MARCHET, Thin Films of Na0.5Bi0.5TiO3 Deposited by Spin-Coating Integrated Ferroelectrics. ,vol. 61, pp. 163- 165 ,(2004) , 10.1080/10584580490459107
Y F Gong, P Wu, X Hai, W F Liu, S Y Wang, G Y Liu, G H Rao, Enhanced dielectric and magnetic properties in Ru-substituted Bi0.9La0.1FeO3 ceramics Journal of Physics D. ,vol. 45, pp. 355001- ,(2012) , 10.1088/0022-3727/45/35/355001
Ya-Ru Zhang, Jing-Feng Li, Bo-Ping Zhang, Chun-E Peng, Piezoelectric and ferroelectric properties of Bi-compensated (Bi1/2Na1/2 )TiO3-(Bi1/2K1/2)TiO3 lead-free piezoelectric ceramics Journal of Applied Physics. ,vol. 103, pp. 074109- ,(2008) , 10.1063/1.2902805
Jinbao Xu, Yun Liu, Ray L. Withers, Frank Brink, Hui Yang, Mark Wang, Ferroelectric and non-linear dielectric characteristics of Bi0.5Na0.5TiO3 thin films deposited via a metallorganic decomposition process Journal of Applied Physics. ,vol. 104, pp. 116101- ,(2008) , 10.1063/1.3032893
Changhong Yang, Jianru Han, Xiufeng Cheng, Xin Yin, Zhuo Wang, Minglei Zhao, Chunlei Wang, Dielectric and ferroelectric properties of (Na0.8K0.2)0.5Bi0.5TiO3 thin films prepared by metalorganic solution deposition Applied Physics Letters. ,vol. 87, pp. 192901- ,(2005) , 10.1063/1.2126129
Eric Cross, Materials science: Lead-free at last Nature. ,vol. 432, pp. 24- 25 ,(2004) , 10.1038/NATURE03142
X.J. Zheng, S.H. Dai, X. Feng, T. Zhang, D.Z. Zhang, Y.Q. Gong, Y.Q. Chen, L. He, Structural and electrical properties of (Na0.85K0.15)0.5Bi0.5TiO3 thin films deposited on LaNiO3 and Pt bottom electrodes Applied Surface Science. ,vol. 256, pp. 3316- 3320 ,(2010) , 10.1016/J.APSUSC.2009.12.026
N. J. Donnelly, G. Catalan, C. Morros, R. M. Bowman, J. M. Gregg, Dielectric and electromechanical properties of Pb(Mg1/3,Nb2/3)O3–PbTiO3 thin films grown by pulsed laser deposition Journal of Applied Physics. ,vol. 93, pp. 9924- 9929 ,(2003) , 10.1063/1.1574181