Phosphorus Removal by Steel Slag Filters: Modeling Dissolution and Precipitation Kinetics to Predict Longevity

作者: Dominique Claveau-Mallet , Benoît Courcelles , Yves Comeau

DOI: 10.1021/ES500689T

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摘要: This article presents an original numerical model suitable for longevity prediction of alkaline steel slag filters used phosphorus removal. The includes kinetic rates dissolution, hydroxyapatite and monetite precipitation the transformation into hydroxyapatite. equations exhaustion. Short-term batch tests using continuous pH monitoring were conducted. parameters calibrated on these experimental results correctly reproduced. was then transposed to long-term flow simulations software PHREEQC. Column run test effect influent P concentration, inorganic C concentration void hydraulic retention time filter capacity. High C, low voids reduced longevity. provided realistic breakthrough at column outlet. Re...

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