Sub-Monolayer Growth of Titanium, Cobalt, and Palladium on Epitaxial Graphene

作者: Anastasia Sokolova , Franziska Kilchert , Stefan Link , Alexander Stöhr , Ulrich Starke

DOI: 10.1002/ANDP.201700031

关键词:

摘要: We deposited metals (Ti, Co, Pd) typically used as seed layers for contacts on epitaxial graphene SiC(0001) and studied the early stages of growth in sub-monolayer regime by Scanning Tunneling Microscopy (STM). All three do not wet substrate Ostwalt ripening occurs at temperatures below 400 K. The analysis orientation metal adislands revealed their specific alignment to lattice. It is found that apparent height islands measured STM strongly deviates from true topographic height. This interpreted an indication presence scattering processes within particles increase transparency metal-graphene interface electrons. Even large are easily picked up tip allowing insight into bonding between island surface mechanisms leading intercalation.

参考文章(41)
Xiaojie Liu, Yong Han, James W. Evans, Albert K. Engstfeld, R. Juergen Behm, Michael C. Tringides, Myron Hupalo, Hai-Qing Lin, Li Huang, Kai-Ming Ho, David Appy, Patricia A. Thiel, Cai-Zhuang Wang, Growth morphology and properties of metals on graphene Progress in Surface Science. ,vol. 90, pp. 397- 443 ,(2015) , 10.1016/J.PROGSURF.2015.07.001
Alpha T. N’Diaye, Sebastian Bleikamp, Peter J. Feibelman, Thomas Michely, Two-dimensional Ir cluster lattice on a graphene Moiré on Ir(111) Physical Review Letters. ,vol. 97, pp. 215501- ,(2006) , 10.1103/PHYSREVLETT.97.215501
Maria Politou, Inge Asselberghs, Iuliana Radu, Thierry Conard, Olivier Richard, Chang Seung Lee, Koen Martens, Safak Sayan, Cedric Huyghebaert, Zsolt Tokei, Stefan De Gendt, Marc Heyns, Transition metal contacts to graphene Applied Physics Letters. ,vol. 107, pp. 153104- ,(2015) , 10.1063/1.4933192
Montserrat Manadé, Francesc Viñes, Francesc Illas, Transition metal adatoms on graphene: A systematic density functional study Carbon. ,vol. 95, pp. 525- 534 ,(2015) , 10.1016/J.CARBON.2015.08.072
Wayne K. Morrow, Stephen J. Pearton, Fan Ren, Review of Graphene as a Solid State Diffusion Barrier. Small. ,vol. 12, pp. 120- 134 ,(2016) , 10.1002/SMLL.201501120
Andrew L. Walter, Shu Nie, Aaron Bostwick, Keun Su Kim, Luca Moreschini, Young Jun Chang, Davide Innocenti, Karsten Horn, Kevin F. McCarty, Eli Rotenberg, Electronic structure of graphene on single-crystal copper substrates Physical Review B. ,vol. 84, pp. 195443- ,(2011) , 10.1103/PHYSREVB.84.195443
Leibo Hu, Xianru Hu, Xuebin Wu, Chenlei Du, Yunchuan Dai, Jianbo Deng, Density functional calculation of transition metal adatom adsorption on graphene Physica B-condensed Matter. ,vol. 405, pp. 3337- 3341 ,(2010) , 10.1016/J.PHYSB.2010.05.001
Q. J. Wang, J. G. Che, Origins of Distinctly Different Behaviors of Pd and Pt Contacts on Graphene Physical Review Letters. ,vol. 103, pp. 066802- ,(2009) , 10.1103/PHYSREVLETT.103.066802
Cheng Gong, Geunsik Lee, Bin Shan, Eric M. Vogel, Robert M. Wallace, Kyeongjae Cho, First-principles study of metal–graphene interfaces Journal of Applied Physics. ,vol. 108, pp. 123711- ,(2010) , 10.1063/1.3524232
C. Virojanadara, S. Watcharinyanon, A. A. Zakharov, L. I. Johansson, Epitaxial graphene on 6H-SiC and Li intercalation Physical Review B. ,vol. 82, pp. 205402- ,(2010) , 10.1103/PHYSREVB.82.205402