Reaction modeling on the phosphorous-treated Ru/Co/Zr/SiO2 Fischer–Tropsch catalyst with the estimation of kinetic parameters and hydrocarbon distribution
作者： Seung-Ho Kwack , Jong Wook Bae , Myung-June Park , Seung-Moon Kim , Kyoung-Su Ha
DOI: 10.1016/J.FUEL.2011.01.010
关键词:
摘要: Abstract The catalytic performances and the kinetics model of cobalt-based Fischer–Tropsch (FT) catalyst were investigated on Ru/Co/Zr/SiO 2 with different amounts phosphorous. preliminary analysis CO conversion, hydrocarbon selectivity activation energy revealed that 0.5 wt.% phosphorous-treated was found to have highest activity because good dispersion cobalt species suppressed aggregation during FT reaction. Kinetics concomitantly developed selected catalyst. reported in literature modified order explain characteristics observed experimental studies, kinetic parameters estimated fit data under various reaction conditions. simulation results along satisfactorily predicted effects operating conditions both conversion entire distribution.
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