Bismuth(III) Trifluoromethanesulfonate

作者: Thierry Ollevier , Etienne Nadeau , Valerie Desyroy

DOI: 10.1002/047084289X.RN00959

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摘要: [88189-03-1] Bi(OSO2CF3)3 (MW 656.19) InChI = 1S/3CHF3O3S.Bi/c3*2-1(3,4)8(5,6)7;/h3*(H,5,6,7);/q;;;+3/p-3 InChIKey = NYENCOMLZDQKNH-UHFFFAOYSA-K Alternate Names: bismuth(III) trifluoromethanesulfonate, bismuth(III) triflate. Physical Data: mp > 300 °C. Solubility: sol organics (CH3CN, dioxane, DMF, DMSO, etc.); reacts with alcohols, amines, and reversibly water. Form Supplied in: white solid, widely available. Handling, Storage, Precautions: Bi(OTf)3 is an hygroscopic salt should be protected from moisture. Preparation: from Bi2O3,1 Bi(O2CCF3)3,2 BiPh3.3

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