Heterocycles in organic synthesis. Part 3. Reversible dearomatisation of azoles: formation of triazabenzophenanthrenes

作者: Avijit Banerji , Julian C. Cass , Alan R. Katritzky

DOI: 10.1039/P19770001162

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摘要: Benzimidazole undergoes reversible dearomatisation with 2,2′-iminodibenzoyl chloride to yield a triazahexacyclic compound (8a). Analogous cyclisations succeeded 5,6-dimethylbenzimidazole and 4-quinazolone, acyclic amidines. Imidazole itself yields the diazocine derivative (19).

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