Synthesis, properties, molecular structure and electron transfer salts of 13,13,14,14-tetracyano-1,6- and -1,8-pyrenoquinodimethanes (1,6-TCNP and 1,8-TCNP)
作者： Ken‐ichi Sugiura , Shinji Mikami , Kentaro Iwasaki , Shojun Hino , Eiji Asato
DOI: 10.1039/A907251I
关键词:
摘要: A guideline for a stable π-extended Wurster type redox system is proposed and two new acceptor molecules having pyrene π-system were prepared structurally characterised. 3,8-Bis(3′,5′-di-tert-butylphenyl)-13,13,14,14-tetracyano-1,6-pyrenoquinodimethane gave an electron transfer complex with Mn(TPP) (H2TPP = m-tetraphenylporphyrin) containing coordination bond.
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