Free-standing molybdenum disulfide/graphene composite paper as a binder- and carbon-free anode for lithium-ion batteries

作者: MinHo Yang , Seunghyun Ko , Ji Sun Im , Bong Gill Choi

DOI: 10.1016/J.JPOWSOUR.2015.04.063

关键词:

摘要: Abstract Two dimensional nanosheets, such as graphene and metal disulfides, have attracted a great deal of attention anode materials for lithium-ion batteries, owing to their unique capability storage. In this work, we integrate MoS 2 nanosheets into free standing film form using simple vacuum filtration method. As-prepared composite could be readily employed binder- carbon-free removing the polymeric binders conductive carbon additives that are required preparation conventional electrodes. addition, interconnected structure sheets provide good electrical conductivity entire electrode. When tested electrochemical performance an electrode exhibits superior compared exfoliated electrode, 65.8% capacity retention at high current rate 1000 mA g −1 91.1% after 100 cycles.

参考文章(37)
P. A. Bertrand, Surface-phonon dispersion of MoS2. Physical Review B. ,vol. 44, pp. 5745- 5749 ,(1991) , 10.1103/PHYSREVB.44.5745
Jie Xiao, Daiwon Choi, Lelia Cosimbescu, Phillip Koech, Jun Liu, John P. Lemmon, Exfoliated MoS2 Nanocomposite as an Anode Material for Lithium Ion Batteries Chemistry of Materials. ,vol. 22, pp. 4522- 4524 ,(2010) , 10.1021/CM101254J
J.-M. Tarascon, M. Armand, Issues and challenges facing rechargeable lithium batteries Nature. ,vol. 414, pp. 359- 367 ,(2001) , 10.1038/35104644
Zhen Wang, Tao Chen, Weixiang Chen, Kun Chang, Lin Ma, Guochuang Huang, Dongyun Chen, Jim Yang Lee, CTAB-assisted synthesis of single-layer MoS2–graphene composites as anode materials of Li-ion batteries Journal of Materials Chemistry. ,vol. 1, pp. 2202- 2210 ,(2013) , 10.1039/C2TA00598K
A Vadivel Murugan, Mathieu Quintin, Marie-Helene Delville, Guy Campet, Chinnakonda S Gopinath, K Vijayamohanan, None, Exfoliation-induced nanoribbon formation of poly(3,4-ethylene dioxythiophene) PEDOT between MoS2 layers as cathode material for lithium batteries Journal of Power Sources. ,vol. 156, pp. 615- 619 ,(2006) , 10.1016/J.JPOWSOUR.2005.06.022
Bruno Scrosati, Jürgen Garche, Lithium batteries: Status, prospects and future Journal of Power Sources. ,vol. 195, pp. 2419- 2430 ,(2010) , 10.1016/J.JPOWSOUR.2009.11.048
Bong Gill Choi, HoSeok Park, Tae Jung Park, Min Ho Yang, Joon Sung Kim, Sung-Yeon Jang, Nam Su Heo, Sang Yup Lee, Jing Kong, Won Hi Hong, Solution chemistry of self-assembled graphene nanohybrids for high-performance flexible biosensors. ACS Nano. ,vol. 4, pp. 2910- 2918 ,(2010) , 10.1021/NN100145X
Dongxing Yang, Aruna Velamakanni, Gülay Bozoklu, Sungjin Park, Meryl Stoller, Richard D. Piner, Sasha Stankovich, Inhwa Jung, Daniel A. Field, Carl A. Ventrice, Rodney S. Ruoff, Chemical analysis of graphene oxide films after heat and chemical treatments by X-ray photoelectron and Micro-Raman spectroscopy Carbon. ,vol. 47, pp. 145- 152 ,(2009) , 10.1016/J.CARBON.2008.09.045
Goki Eda, Hisato Yamaguchi, Damien Voiry, Takeshi Fujita, Mingwei Chen, Manish Chhowalla, Photoluminescence from Chemically Exfoliated MoS2 Nano Letters. ,vol. 11, pp. 5111- 5116 ,(2011) , 10.1021/NL201874W
Jae-Min Jeong, Kyoung G. Lee, Sung-Jin Chang, Jung Won Kim, Young-Kyu Han, Seok Jae Lee, Bong Gill Choi, Ultrathin sandwich-like MoS2@N-doped carbon nanosheets for anodes of lithium ion batteries Nanoscale. ,vol. 7, pp. 324- 329 ,(2015) , 10.1039/C4NR06215A