V-doped TiO2 supported Pt as a promising oxygen reduction reaction catalyst: Synthesis, characterization and in-situ evaluation in proton exchange membrane fuel cell
作者： Abha Bharti , Gouri Cheruvally
DOI: 10.1016/J.JPOWSOUR.2017.07.111
关键词:
摘要: Abstract This study deals with the synthesis and characterization of V-doped, TiO 2 supported Pt catalyst (Pt/V-TiO ) for oxygen reduction reaction (ORR) its in-situ performance investigation in proton exchange membrane (PEM) fuel cell. Pt/V-TiO nanocomposite is prepared via a facile sol-gel microwave assisted, modified chemical route compared undoped catalyst, Pt/TiO an identical way. The catalysts are employed as cathode PEM cell standard Pt/C catalyst. Their comparative studies conducted physical electrochemical techniques. In-situ show improved ORR catalytic activity to . Furthermore, both more stable than when subjected 6000 voltammetric cycles range 0.2–1.2 V vs hydrogen electrode operating conditions, losing only material potential immense scope further investigation.
harvard.edu
elsevier.com
sci-hub.se 参考文章(42)
Samira Farsinezhad, Himani Sharma, Karthik Shankar, Interfacial band alignment for photocatalytic charge separation in TiO2 nanotube arrays coated with CuPt nanoparticles. Physical Chemistry Chemical Physics. ,vol. 17, pp. 29723- 29733 ,(2015) , 10.1039/C5CP05679A
Konstantinos C. Christoforidis, Marcos Fernández-García, Photoactivity and charge trapping sites in copper and vanadium doped anatase TiO2 nano-materials Catalysis Science & Technology. ,vol. 6, pp. 1094- 1105 ,(2016) , 10.1039/C5CY00929D
Sanjeev Mukerjee, James McBreen, Effect of particle size on the electrocatalysis by carbon-supported Pt electrocatalysts: an in situ XAS investigation Journal of Electroanalytical Chemistry. ,vol. 448, pp. 163- 171 ,(1998) , 10.1016/S0022-0728(97)00018-1
Denitsa Shopova-Gospodinova, Lars P.H. Jeurgens, Udo Welzel, Luciana Pitta Bauermann, Rudolf C. Hoffmann, Joachim Bill, Synthesis of V-doped TiO2 films by chemical bath deposition and the effect of post-annealing on their properties Thin Solid Films. ,vol. 520, pp. 5928- 5935 ,(2012) , 10.1016/J.TSF.2012.03.047
S. Wang, L.N. Bai, H.M. Sun, Q. Jiang, J.S. Lian, Structure and photocatalytic property of Mo-doped TiO2 nanoparticles Powder Technology. ,vol. 244, pp. 9- 15 ,(2013) , 10.1016/J.POWTEC.2013.03.054
L. Samet, J. Ben Nasseur, R. Chtourou, K. March, O. Stephan, Heat treatment effect on the physical properties of cobalt doped TiO2 sol–gel materials Materials Characterization. ,vol. 85, pp. 1- 12 ,(2013) , 10.1016/J.MATCHAR.2013.08.007
S. Wang, J.S. Lian, W.T. Zheng, Q. Jiang, Photocatalytic property of Fe doped anatase and rutile TiO2 nanocrystal particles prepared by sol–gel technique Applied Surface Science. ,vol. 263, pp. 260- 265 ,(2012) , 10.1016/J.APSUSC.2012.09.040
Ken Elen, Boris Capon, Christopher De Dobbelaere, Daan Dewulf, Nick Peys, Christophe Detavernier, An Hardy, Marlies K. Van Bael, Transparent conducting oxide films of group V doped titania prepared by aqueous chemical solution deposition Thin Solid Films. ,vol. 555, pp. 33- 38 ,(2014) , 10.1016/J.TSF.2013.05.104
Jingjing Xu, Yanhui Ao, Mindong Chen, Degang Fu, Chunwei Yuan, Photocatalytic activity of vanadium-doped titania–activated carbon composite film under visible light Thin Solid Films. ,vol. 518, pp. 4170- 4174 ,(2010) , 10.1016/J.TSF.2009.12.005
Huimin Wu, David Wexler, Huakun Liu, Pt–Ni/C catalysts using different carbon supports for the cathode of the proton exchange membrane fuel cell (PEMFC) Materials Chemistry and Physics. ,vol. 136, pp. 845- 849 ,(2012) , 10.1016/J.MATCHEMPHYS.2012.08.007