Voltammetric Study of Organic Metals. I. The Determination of the Electrochemical Conditions for Crystal Growth

作者: Sachiko Sakura , Hideo Imai , Hiroyuki Anzai , Tetsuo Moriya

DOI: 10.1246/BCSJ.61.3181

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摘要: The metallic crystals of organic charge-transfer complexes are grown by means the electrolytic oxidation tetrathiafulvalene (TTF) derivatives in presence trihalide anions solvents. In order to obtain a crystal good quality, optimal conditions for growth have been searched based on data cyclic voltammetry. this paper, electrochemical conditions, such as potential, stability donor monocation radicals, and redox behavior under potential donors, discussed relation chemical reactions proceeding solution during growth.

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