Gas phase chemistry of N-benzylbenzamides with silver(I) cations: characterization of benzylsilver cation
作者： Hezhi Sun , Zhe Jin , Hong Quan , Cuirong Sun , Yuanjiang Pan
DOI: 10.1039/C4OB02355B
关键词:
摘要: The benzylsilver cation which emerges from the collisional dissociation of silver(I)–N-benzylbenzamide complexes was characterized by deuterium-labeling experiments, theoretical calculations, breakdown curves and substituent effects. nucleophilic attack carbonyl oxygen on an α-hydrogen results in generation cation, is competitive to AgH loss with α-hydrogen.
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