作者: Xianguang Huang , Li Wang , Wantai Yang
DOI: 10.1039/C5PY00703H
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摘要: A simple and novel synthetic route toward core–shell polymeric particles via surface-initiated cycloketyl radical mediated living polymerization (CMP) is presented. Cross-linked polymaleic anhydride/isoprene (CPMIP) prepared by self-stable precipitation were reacted with 9,9′-bixanthydrol (BIXANDL), which endowed them potential initiating sites for subsequent CMP of styrene, methyl methacrylate n-butyl acrylate. Uniform successfully obtained in all cases their sizes increased continuous monomer conversion, demonstrating the versatility feature CMP.