Hybrid Core@Soft Shell Particles as Adhesive Elementary Building Blocks for Colloidal Crystals

摘要: Hybrid materials have been developed through the synthesis of colloidal silica surrounded by elastomer polymer brushes. These core@shell achieved use “nitroxide-mediated polymerization” (NMP) associated with a “grafting from” method. The living and controlled characteristics polymerization allow TEM observations well-monodisperse nanohybrids. We present herein synthetic process to create homogeneous smoothness particles surface strong adhesive property. brush thickness is tuned in order compare molecular dynamic equations tailoring grafting density weight. Finally, these were used as elementary building blocks self-assembled dip-coating form monolayered material. Its diffraction under light described on large-scale material well elastomeric brushes layer influence.