Analysis of the B2Σ+ ∼ A2Πi perturbations in the CN(B2Σ+-X2Σ+) main band system

作者: Haruhiko Ito , Yasushi Ozaki , Kaoru Suzuki , Tamotsu Kondow , Kozo Kuchitsu

DOI: 10.1016/0022-2852(88)90121-X

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摘要: Abstract The CN( B 2 Σ + - X ) main band transitions (0 ≤ v ′ 9) observed by H. S. Uhler and R. A. Patterson were assigned, a number of local perturbations between the , = 0–9 A Π i 11–24 levels occurring at 30 ≲ J 140 analyzed. molecular constants for states including higher-order centrifugal distortion constants, E D H Δ L M N determined, where represents difference states. 0-0 Engleman was also reanalyzed, perturbation 0 ∼ 10 redetermined. electronic terms interaction matrix elements, el SO RE determined in present study found to be nearly constant good agreement with those our previous analysis system.

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