Catalytic behaviour of a novel Fe(III) Schiff base complex in the mild oxidation of cyclohexane
作者： Dmytro S. Nesterov , Oksana V. Nesterova , M. Fátima C. Guedes da Silva , Armando J. L. Pombeiro
DOI: 10.1039/C4CY00888J
关键词:
摘要: The complex [FeIII (HL) Cl2 (DMF)] Cl· DMF (1) was synthesized by reaction of Fe (III) chloride with a dimethylformamide solution of the Schiff base aminoalcohol HL (2-[(E)-{[2-(piperazin-1-yl) ethyl] imino} methyl] phenol) and characterized by single crystal X-ray diffraction analysis, thermogravimetry and spectroscopic methods. The catalytic investigations disclosed a marked activity of 1 towards oxidation of cyclohexane with hydrogen peroxide, under mild conditions, with yields based on cyclohexane up to 37% and …
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