The Molecular and Electronic Structure of Octahedral Tris(phenolato)iron(III) Complexes and Their Phenoxyl Radical Analogues: A Mössbauer and Resonance Raman Spectroscopic Study
作者： Michael D. Snodin , Lynda Ould-Moussa , Ursula Wallmann , Sophie Lecomte , Vinzenz Bachler
DOI: 10.1002/(SICI)1521-3765(19990903)5:9<2554::AID-CHEM2554>3.0.CO;2-H
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摘要: One, two, and three coordinated phenoxyl radicals are formed by a series of differently substituted tris(phenolato)iron(III) complexes, [FeIIIL], which undergo reversible one-electron oxidations. The cations [FeIIIL]+. [FeIIIL]2+.. have been characterized zero- applied field Mossbauer resonance Raman spectroscopy. Both techniques prove unambiguously independently that these oxidations ligand- rather than metal-centered processes.
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