Dependence of the magnetic state of polyaniline on moisture

作者: P K Kahol , B J McCormick

DOI: 10.1088/0953-8984/3/40/017

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摘要: The presence of water enhances the conduction process polyaniline in protonated emeraldine-base form. Through magnetic susceptibility measurements on thermally aged samples it is shown that Pauli susceptibility, which related to extent conduction, and Curie are sensitively dependent moisture. It suggested same spin can contribute either or depending its environment temperature, water, even small amounts, may determine dynamical behaviour spins.

参考文章(16)
A. J. Epstein, A. G. MacDiarmid, J. P. Pouget, Spin dynamics and conductivity in polyaniline. Physical Review Letters. ,vol. 65, pp. 664- 664 ,(1990) , 10.1103/PHYSREVLETT.65.664
M. Nechtschein, C. Santier, J.P. Travers, J. Chroboczek, A. Alix, M. Ripert, Water effects in polyaniline: NMR and transport properties Synthetic Metals. ,vol. 18, pp. 311- 316 ,(1987) , 10.1016/0379-6779(87)90897-6
H. H. S. Javadi, K. R. Cromack, A. G. MacDiarmid, A. J. Epstein, Microwave transport in the emeraldine form of polyaniline Physical Review B. ,vol. 39, pp. 3579- 3584 ,(1989) , 10.1103/PHYSREVB.39.3579
J.-P. Travers, F. Genoud, C. Menardo, M. Nechtschein, Polyaniline: A material still under discussion Synthetic Metals. ,vol. 35, pp. 159- 168 ,(1990) , 10.1016/0379-6779(90)90040-R
K. Mizoguchi, M. Nechtschein, J. P. Travers, Mizoguchi, Nechtschein, and Travers reply. Physical Review Letters. ,vol. 65, pp. 665- 665 ,(1990) , 10.1103/PHYSREVLETT.65.665
Jin-Chih Chiang, Alan G MacDiarmid, ‘Polyaniline’: Protonic acid doping of the emeraldine form to the metallic regime Synthetic Metals. ,vol. 13, pp. 193- 205 ,(1986) , 10.1016/0379-6779(86)90070-6
A.J Epstein, J.M Ginder, F Zuo, R.W Bigelow, H.-S Woo, D.B Tanner, A.F Richter, W.-S Huang, A.G MacDiarmid, Insulator-to-metal transition in polyaniline Synthetic Metals. ,vol. 18, pp. 303- 309 ,(1987) , 10.1016/0379-6779(87)90896-4
Marie Angelopoulos, Anjan Ray, Alan G Macdiarmid, Arthur J Epstein, Polyaniline: Processability from aqueous solutions and effect of water vapor on conductivity Synthetic Metals. ,vol. 21, pp. 21- 30 ,(1987) , 10.1016/0379-6779(87)90062-2
Alan G. Macdiarmid, Jin-Chih Chiang, Wusong Huang, Brian D. Humphrey, N. L. D. Somasiri, Polyaniline: Protonic Acid Doping to the Metallic Regime Molecular Crystals and Liquid Crystals. ,vol. 125, pp. 309- 318 ,(1985) , 10.1080/00268948508080110
J. P. Pouget, M. E. Jozefowicz, A. J. Epstein, X. Tang, A. G. MacDiarmid, X-ray structure of polyaniline Macromolecules. ,vol. 24, pp. 779- 789 ,(1991) , 10.1021/MA00003A022