Three-Dimensional Pyrene-Fused N-Heteroacenes
作者： Ben-Lin Hu , Cunbin An , Manfred Wagner , Georgia Ivanova , Anela Ivanova
DOI: 10.1021/JACS.9B01082
关键词:
摘要: Four three-dimensional (3D) pyrene-fused N-heteroacenes (P1-P4) are designed and synthesized. From P1 to P4, their lengths extended in an iterative way, where the thiadiazole unit can be reduced diamine obtained diamines further condensed with diketones a unit. Compared two-dimensional counterparts, solubility of these 3D is improved by this covalent linkage units. The diameters P1-P4 3.66, 6.06, 8.48 10.88 nm, respectively, molecules characterized 1H, 13C 2D NMR, MS, UV-vis, PL CV spectra. Our strategy shows promising way large N-heteroacenes.
acs.org
mpg.de
sci-hub.se 参考文章(41)
Pei-Yang Gu, Zongrui Wang, Guangfeng Liu, Huiying Yao, Zilong Wang, Yang Li, Jia Zhu, Shuzhou Li, Qichun Zhang, Synthesis, Full Characterization, and Field Effect Transistor Behavior of a Stable Pyrene-Fused N-Heteroacene with Twelve Linearly Annulated Six-Membered Rings Chemistry of Materials. ,vol. 29, pp. 4172- 4175 ,(2017) , 10.1021/ACS.CHEMMATER.7B01318
Zilong Wang, Peiyang Gu, Guangfeng Liu, Huiying Yao, Yishi Wu, Yongxin Li, Ganguly Rakesh, Jia Zhu, Hongbing Fu, Qichun Zhang, A large pyrene-fused N-heteroacene: fifteen aromatic six-membered rings annulated in one row Chemical Communications. ,vol. 53, pp. 7772- 7775 ,(2017) , 10.1039/C7CC03898D
Lei Ji, Alexandra Friedrich, Ivo Krummenacher, Antonius Eichhorn, Holger Braunschweig, Michael Moos, Sebastian Hahn, Florian L Geyer, Olena Tverskoy, Jie Han, Christoph Lambert, Andreas Dreuw, Todd B Marder, Uwe HF Bunz, None, Preparation, Properties, and Structures of the Radical Anions and Dianions of Azapentacenes Journal of the American Chemical Society. ,vol. 139, pp. 15968- 15976 ,(2017) , 10.1021/JACS.7B09460
Ben-Lin Hu, Ke Zhang, Cunbin An, Wojciech Pisula, Martin Baumgarten, Thiadiazoloquinoxaline-Fused Naphthalenediimides for n-Type Organic Field-Effect Transistors (OFETs). Organic Letters. ,vol. 19, pp. 6300- 6303 ,(2017) , 10.1021/ACS.ORGLETT.7B03041
Diego Cortizo‐Lacalle, Juan P. Mora‐Fuentes, Karol Strutyński, Akinori Saeki, Manuel Melle‐Franco, Aurelio Mateo‐Alonso, Monodisperse N-Doped Graphene Nanoribbons Reaching 7.7 Nanometers in Length. Angewandte Chemie. ,vol. 57, pp. 703- 708 ,(2018) , 10.1002/ANIE.201710467
David Leibold, Vincent Lami, Yvonne J Hofstetter, David Becker‐Koch, Andreas Weu, Philipp Biegger, Fabian Paulus, Uwe HF Bunz, Paul E Hopkinson, Artem A Bakulin, Yana Vaynzof, None, Triptycenyl‐phenazino‐thiadiazole as acceptor in organic bulk-heterojunction solar cells Organic Electronics. ,vol. 57, pp. 285- 291 ,(2018) , 10.1016/J.ORGEL.2018.03.001
Yuki Inoue, Daisuke Sakamaki, Yusuke Tsutsui, Masayuki Gon, Yoshiki Chujo, Shu Seki, Hash-Mark-Shaped Azaacene Tetramers with Axial Chirality. Journal of the American Chemical Society. ,vol. 140, pp. 7152- 7158 ,(2018) , 10.1021/JACS.8B02689
Anita Das, Max Pinheiro, Francisco B. C. Machado, Adélia J. A. Aquino, Hans Lischka, Tuning the Biradicaloid Nature of Polycyclic Aromatic Hydrocarbons: The Effect of Graphitic Nitrogen Doping in Zethrenes. ChemPhysChem. ,vol. 19, pp. 2492- 2499 ,(2018) , 10.1002/CPHC.201800650
Ben-Lin Hu, Ke Zhang, Cunbin An, Dieter Schollmeyer, Wojciech Pisula, Martin Baumgarten, Layered Thiadiazoloquinoxaline-Containing Long Pyrene-Fused N-Heteroacenes. Angewandte Chemie. ,vol. 57, pp. 12375- 12379 ,(2018) , 10.1002/ANIE.201803230
Herbert Zimmermann, Franz Kummer, Über die Elektronenspektren linearer Diaza‐ und Tetraaza‐Acene Berichte der Bunsengesellschaft für physikalische Chemie. ,vol. 71, pp. 1119- 1126 ,(1967) , 10.1002/BBPC.19670710922