Layered Thiadiazoloquinoxaline-Containing Long Pyrene-Fused N-Heteroacenes.

作者: Ben-Lin Hu , Ke Zhang , Cunbin An , Dieter Schollmeyer , Wojciech Pisula

DOI: 10.1002/ANIE.201803230

关键词:

摘要: Three thiadiazoloquinoxaline-containing long pyrene-fused N-heteroacenes with 8, 13, and 18 rings were designed synthesized. They show high electron affinities (EAs) of approximately 4.1 eV, which derived from the onset reduction peaks in cyclic voltammetry. Crystal structure analysis revealed in-plane extension through close contacts between thiadiazole units as well layered packing, enabling interlayer transport. Organic field-effect transistor devices provided mobilities, suggest a potential way to enhance charge transport N-heteroacenes.

参考文章(36)
Philipp Biegger, Manuel Schaffroth, Kerstin Brödner, Olena Tverskoy, Frank Rominger, Uwe HF Bunz, None, Bisalkynylated 3,6-diiminocyclohexa-1,4-diene-1,4-diamine Chemical Communications. ,vol. 51, pp. 14844- 14847 ,(2015) , 10.1039/C5CC05427C
Aurelio Mateo-Alonso, Pyrene-fused pyrazaacenes: from small molecules to nanoribbons Chemical Society Reviews. ,vol. 43, pp. 6311- 6324 ,(2014) , 10.1039/C4CS00119B
Benjamin D Lindner, Jens U Engelhart, Olena Tverskoy, Anthony Lucas Appleton, Frank Rominger, Anastasia Peters, Hans‐Jörg Himmel, Uwe HF Bunz, None, Stabile Hexacene durch Stickstoffsubstitution Angewandte Chemie. ,vol. 123, pp. 8747- 8750 ,(2011) , 10.1002/ANGE.201103676
Uwe HF Bunz, Jens U Engelhart, Benjamin D Lindner, Manuel Schaffroth, None, Große N‐Heteroacene: ein alter Hut mit neuen Federn? Angewandte Chemie. ,vol. 125, pp. 3898- 3910 ,(2013) , 10.1002/ANGE.201209479
Gang Qian, Ze Zhong, Min Luo, Dengbin Yu, Zhiqiang Zhang, Dongge Ma, Zhi Yuan Wang, Synthesis and Application of Thiadiazoloquinoxaline-Containing Chromophores as Dopants for Efficient Near-Infrared Organic Light-Emitting Diodes Journal of Physical Chemistry C. ,vol. 113, pp. 1589- 1595 ,(2009) , 10.1021/JP809568A
Jörn Pommerehne, Horst Vestweber, Werner Guss, Rainer F. Mahrt, Heinz Bässler, Michael Porsch, Jörg Daub, Efficient two layer leds on a polymer blend basis Advanced Materials. ,vol. 7, pp. 551- 554 ,(1995) , 10.1002/ADMA.19950070608
Bernd Kohl, Frank Rominger, Michael Mastalerz, Ein Pyren-fusioniertes N-Heteroacen mit elf linear anellierten aromatischen Ringen† Angewandte Chemie. ,vol. 127, pp. 6149- 6154 ,(2015) , 10.1002/ANGE.201411972
Baoxiang Gao, Ming Wang, Yanxiang Cheng, Lixiang Wang, Xiabin Jing, Fosong Wang, Pyrazine-containing acene-type molecular ribbons with up to 16 rectilinearly arranged fused aromatic rings. Journal of the American Chemical Society. ,vol. 130, pp. 8297- 8306 ,(2008) , 10.1021/JA800311A