Bisalkynylated 3,6-diiminocyclohexa-1,4-diene-1,4-diamine

作者: Philipp Biegger , Manuel Schaffroth , Kerstin Brödner , Olena Tverskoy , Frank Rominger

DOI: 10.1039/C5CC05427C

关键词: Polymer chemistryDiamineElectrochemistryDieneChemistryOrganic chemistryQuantum chemicalCondensation reaction

摘要: Reduction of bis(benzothiadiazol) by LiAlH4/CuI gives diethynylated diaminobenzoquinoneimine. This building block accesses novel targets in a one-step condensation reaction with different ortho-quinones, resulting unexpected rearrangement products. The compounds are characterized their photophysical and electrochemical data as well quantum chemical calculations.

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