作者: Philipp Biegger , Manuel Schaffroth , Kerstin Brödner , Olena Tverskoy , Frank Rominger
DOI: 10.1039/C5CC05427C
关键词: Polymer chemistry 、 Diamine 、 Electrochemistry 、 Diene 、 Chemistry 、 Organic chemistry 、 Quantum chemical 、 Condensation reaction
摘要: Reduction of bis(benzothiadiazol) by LiAlH4/CuI gives diethynylated diaminobenzoquinoneimine. This building block accesses novel targets in a one-step condensation reaction with different ortho-quinones, resulting unexpected rearrangement products. The compounds are characterized their photophysical and electrochemical data as well quantum chemical calculations.