Putting the ‘N’ in ACENE: Pyrazinacenes and their structural relatives
作者： Gary J. Richards , Jonathan P. Hill , Toshiyuki Mori , Katsuhiko Ariga
DOI: 10.1039/C1OB05454F
关键词: Chemistry 、 Acene 、 Electronic properties 、 Antiaromaticity 、 Nanotechnology 、 Aromaticity
摘要: Acenes have emerged as an important class of organic electronic material. Related heteroatom-substituted compounds, or heteroacenes, introduce means for modulating properties and improving materials’ stability. In this perspective, we will review the historical origins heteroacenes discuss recent progress in field acene related compounds containing fused 1,4-diazabenzene units, i.e.pyrazine, also known ‘pyrazinacenes’. We focus not only on types materials that been prepared but their chemical physical properties, including synthetic procedures, self-assembly characteristics, some computational studies aimed at understanding more unusual behaviours group such protic tautomerism aromaticity/antiaromaticity.
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