Catalysts for C–H functionalization: Platinum, gold and even nanodiamonds

摘要: Abstract Investigations of activation C–H bonds in mild conditions have been analyzed. Much attention is given to the Shilov chemistry. The system, namely, platinum (II) and (IV) halides aqueous solution, has demonstrated ability homogenous catalysts activate functionalize saturated hydrocarbons including methane. Gold containing are intensely introduced catalytic For first time, reactions an aerobic anaerobic oxidation methane presence gold complexes environment also shown. High activity selectivity can be attained by developing variously modified nanocarbons, for example, those based on fullerene, fullerene-containing materials even chemically nanodiamonds.