Methylpalladium complexes with pyrimidine-functionalized N-heterocyclic carbene ligands
作者： Dirk Meyer , Thomas Strassner
DOI: 10.3762/BJOC.12.150
关键词:
摘要: A series of methylpalladium(II) complexes with pyrimidine-NHC ligands carrying different aryl- and alkyl substituents R ([((pym)^(NHC-R))Pd(II)(CH3)X] X = Cl, CF3COO, CH3) has been prepared by transmetalation reactions from the corresponding silver chloro(methyl)(cyclooctadiene)palladium(II). The dimethyl(1-(2-pyrimidyl)-3-(2,6-diisopropylphenyl)imidazolin-2-ylidene)palladium(II) complex was synthesized via free carbene route. All were fully characterized standard methods in three cases also a solid state structure.
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