Significantly enhanced dehydrogenation properties of calcium borohydride combined with urea

作者: Hailiang Chu , Shujun Qiu , Lin Liu , Yongjin Zou , Cuili Xiang

DOI: 10.1039/C4DT01355G

关键词:

摘要: The interaction of [BHx]- and [NHx]-containing species gives rise to molecular hydrogen the establishment B–N bond. Up now, metal amides ammonia are commonly used [NHx] sources. Herein, urea, an organic carbonyl diamide, was react with Ca(BH4)2. A new type complex hydride Ca(BH4)2·4CO(NH2)2 synthesized release ca. 5.2 wt% below 250 °C.

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