Cis double allylation of cyclopropenes using cyclopropylindium reagents

作者: Tsunehisa Hirashita , Fumio Shiraki , Kenji Onishi , Mamiko Ogura , Shuki Araki

DOI: 10.1039/B706539F

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摘要: The successive double allylation of cyclopropenes with allylindium sesquiiodide and allyl iodide proceeded a cis-addition mode in the presence other organometallics (e.g. Grignard reagent, cuprate, Et2Zn Et3Al), giving corresponding cis-diallylcyclopropanes high yields.

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