Reactions of cesium perfluorotertiary alkoxides and perfluorotertiary alcohols with reactive halides
作者： Grace J. Chen , Loomis S. Chen
DOI: 10.1016/S0022-1139(96)03474-4
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摘要: Abstract Reactions of cesium perfluorotertiary alkoxides and perfiuorotertiary alcohols with chlorotrimethylsilane, benzoyl chloride, perfluoroacyl halides 3-phenoxybenzoyl chloride gave the compounds Me 3 SiOR f 1 (3), C 6 H 5 C(O)OR ( 4a ), 2 4b R ′C(O)OR 5a 5b ″C(O)OR n-C F 7 ) (3-C 4 O)C 8 where = (CF (n-C 13 )(n-C 17 )C-, [(CF CFO(CF ] CF O[CF CF(CF )O] C-, )[(CF ]C-, ′ O[CF(CF )CF O] )-and ″ OCF(CF )-. The relative thermal hydrolytic stabilities some these 3, were determined.
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