Heterogeneous Aging Within PEMFC Stacks

作者: Y. Chatillon , C. Bonnet , F. Lapicque

DOI: 10.1002/FUCE.201300105

关键词:

摘要: Evaluation of PEM fuel cell aging occurring in various operating conditions is usually conducted single configuration for which electrochemical methods can be used. Aging phenomena stack often investigated either a global manner or by basic measurements variables, e. g. individual voltages. This paper presents the results investigation three-cell stacks using crossed linked giving access to time variations ohmic and charge transfer resistance three cathodes, as well surface area crossover over more than 1,000 h at 0.3 A cm(-2) upon air humidification. Consistency between employed was discussed demonstrated. In addition case formed sane cells, comprising defective - previously aged under oxidative placed two MEAs investigated: pre-ageing this shown slightly accelerate long-term operation. Besides, it observed that both stacks, back i.e. located far from inlet outlet suffered much run other cells.

参考文章(16)
Bo Tao Huang, Yohann Chatillon, Caroline Bonnet, François Lapicque, Sébastien Leclerc, Melika Hinaje, Stéphane Raël, Experimental investigation of pinhole effect on MEA/cell aging in PEMFC International Journal of Hydrogen Energy. ,vol. 38, pp. 543- 550 ,(2013) , 10.1016/J.IJHYDENE.2012.09.058
M. Miller, A. Bazylak, A review of polymer electrolyte membrane fuel cell stack testing Journal of Power Sources. ,vol. 196, pp. 601- 613 ,(2011) , 10.1016/J.JPOWSOUR.2010.07.072
Minoru Inaba, Taro Kinumoto, Masayuki Kiriake, Ryota Umebayashi, Akimasa Tasaka, Zempachi Ogumi, Gas crossover and membrane degradation in polymer electrolyte fuel cells Electrochimica Acta. ,vol. 51, pp. 5746- 5753 ,(2006) , 10.1016/J.ELECTACTA.2006.03.008
Ph. Moçotéguy, B. Ludwig, J. Scholta, R. Barrera, S. Ginocchio, Long Term Testing in Continuous Mode of HT‐PEMFC Based H3PO4/PBI Celtec‐P MEAs for μ‐CHP Applications Fuel Cells. ,vol. 9, pp. 325- 348 ,(2009) , 10.1002/FUCE.200800134
S.J.C. Cleghorn, D.K. Mayfield, D.A. Moore, J.C. Moore, G. Rusch, T.W. Sherman, N.T. Sisofo, U. Beuscher, A polymer electrolyte fuel cell life test: 3 years of continuous operation Journal of Power Sources. ,vol. 158, pp. 446- 454 ,(2006) , 10.1016/J.JPOWSOUR.2005.09.062
P. Moçotéguy, B. Ludwig, J. Scholta, Y. Nedellec, D. J. Jones, J. Rozière, Long‐Term Testing in Dynamic Mode of HT‐PEMFC H3PO4/PBI Celtec‐P Based Membrane Electrode Assemblies for Micro‐CHP Applications Fuel Cells. ,vol. 10, pp. 299- 311 ,(2010) , 10.1002/FUCE.200900153
Hubert A. Gasteiger, Shyam S. Kocha, Bhaskar Sompalli, Frederick T. Wagner, Activity benchmarks and requirements for Pt, Pt-alloy, and non-Pt oxygen reduction catalysts for PEMFCs Applied Catalysis B-environmental. ,vol. 56, pp. 9- 35 ,(2005) , 10.1016/J.APCATB.2004.06.021
Sébastien Wasterlain, Denis Candusso, Fabien Harel, Daniel Hissel, Xavier François, Development of new test instruments and protocols for the diagnostic of fuel cell stacks Journal of Power Sources. ,vol. 196, pp. 5325- 5333 ,(2011) , 10.1016/J.JPOWSOUR.2010.08.029
Yohann Chatillon, Caroline Bonnet, François Lapicque, Differential capacity plot as a tool for determination of electroactive surface area within a PEMFC stack Journal of Applied Electrochemistry. ,vol. 43, pp. 1017- 1026 ,(2013) , 10.1007/S10800-013-0585-7
Kug-Seung Lee, Byung-Seok Lee, Sung Jong Yoo, Soo-Kil Kim, Seung Jun Hwang, Hyung-Juhn Kim, EunAe Cho, Dirk Henkensmeier, Jeong Woo Yun, Suk Woo Nam, Tae-Hoon Lim, Jong Hyun Jang, Development of a galvanostatic analysis technique as an in-situ diagnostic tool for PEMFC single cells and stacks International Journal of Hydrogen Energy. ,vol. 37, pp. 5891- 5900 ,(2012) , 10.1016/J.IJHYDENE.2011.12.152