Nature of electrical charge carriers in the Earth's lower mantle from laboratory measurements

作者: Xiaoyuan Li , Raymond Jeanloz

DOI: 10.1029/94GL01934

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摘要: Thermoelectric power measurements on a silicate-perovskite and magnesiowustite assemblage at lower-mantle conditions [(Mg0.89Fe0.11)2SiO4 bulk composition 48 GPa temperatures up to 2500 K] yield positive Seebeck coefficient, thus implying that the dominant charge carriers are electrons in conduction band (intrinsic carriers) contribute little electrical conductivity. The present results suggest transport is likely dominated by extrinsic throughout entire mantle and, hence, conductivity can be powerful tool for characterizing minor phases, impurities defect states of Earth's deep interior.

参考文章(37)
A. E. Hughes, Optical Techniques and an Introduction to the Symmetry Properties of Point Defects Defects and Their Structure in Nonmetallic Solids. pp. 133- 154 ,(1976) , 10.1007/978-1-4684-2802-5_4
Frank J. Blatt, Thermoelectric Power of Metals ,(1976)
Martin Harold Phillips Bott, The interior of the earth ,(1971)
Charles Richard Arthur Catlow, Peter David Townsend, None, Point Defects in Materials ,(1988)
V. A. Kalinin, V. N. Zharkov, Albin Tybulewicz, Equations of State for Solids at High Pressures and Temperatures ,(1995)
Xiaoyuan Li, Li-Chung Ming, Murli H. Manghnani, Yanbin Wang, Raymond Jeanloz, Pressure dependence of the electrical conductivity of (Mg0.9Fe0.1)SiO3 perovskite Journal of Geophysical Research. ,vol. 98, pp. 501- 508 ,(1993) , 10.1029/92JB01816
I. C. Getting, G. C. Kennedy, Effect of Pressure on the emf of Chromel‐Alumel and Platinum‐Platinum 10% Rhodium Thermocouples Journal of Applied Physics. ,vol. 41, pp. 4552- 4562 ,(1970) , 10.1063/1.1658495
R. Szymanik, B. Staniszewski, S. Wisniewski, Thermodynamics of Nonequilibrium Processes ,(1976)
T. O. Mason, Electrical Studies of Transition Metal Cation Distribution in Spinels Point Defects in Minerals. ,vol. 31, pp. 69- 77 ,(2013) , 10.1029/GM031P0069