Voltammetry of carbon dioxide

作者: Brian R. Eggins , Joanne McNeill

DOI: 10.1016/S0022-0728(83)80127-2

关键词:

摘要: Abstract We have studied voltammetric reduction waves for carbon dioxide in water, dimethylsulphoxide, acetonitrile and propylene carbonate using electrodes of glassy carbon, mercury, platinum, gold lead as applicable. The apparent number electrons involved was determined from the current function some cases by chronoamperometric analysis diffusion controlled tail wave. Results were compared with those other workers.

参考文章(6)
Louis V. Haynes, Donald T. Sawyer, Electrochemistry of carbon dioxide in dimethyl sulfoxide at gold and mercury electrodes Analytical Chemistry. ,vol. 39, pp. 332- 338 ,(1967) , 10.1021/AC60247A013
E. Lamy, L. Nadjo, J.M. Saveant, Standard potential and kinetic parameters of the electrochemical reduction of carbon dioxide in dimethylformamide Journal of Electroanalytical Chemistry. ,vol. 78, pp. 403- 407 ,(1977) , 10.1016/S0022-0728(77)80143-5
Brian R. Eggins, Norman H. Smith, Diffusion control in linear sweep voltammetry Analytical Chemistry. ,vol. 51, pp. 2282- 2283 ,(1979) , 10.1021/AC50049A050
K.S. Udupa, G.S. Subramanian, H.V.K. Udupa, The electrolytic reduction of carbon dioxide to formic acid Electrochimica Acta. ,vol. 16, pp. 1593- 1598 ,(1971) , 10.1016/0013-4686(71)80028-2
A. W. B. Aylmer-Kelly, A. Bewick, P. R. Cantrill, A. M. Tuxford, Studies of electrochemically generated reaction intermediates using modulated specular reflectance spectroscopy Faraday Discussions of The Chemical Society. ,vol. 56, pp. 96- 107 ,(1973) , 10.1039/DC9735600096
Julian L. Roberts, Donald T. Sawyer, Voltammetric determination of carbon dioxide using dimethylsulfoxide as a solvent Journal of Electroanalytical Chemistry. ,vol. 9, pp. 1- 7 ,(1965) , 10.1016/0022-0728(65)80060-2