Azide compositions and methods of making and using thereof

摘要: Azide compositions selected from i) UOCR2CR2N3 wherein U is D, or a urethane (-CO-NR2) and R independently H, an organic group; ii) R'2NCR2CR2N3 A-R'3N CR2CR2N3 R' group A anion; iii) G(N3)m m integer 2 to about 10 G m-valent at least two of the azido groups are connected via aliphatic carbon atoms may contain groups, uses thereof described. Specifically, azide consisting of: N3CH2CH2OCH2CHOHCH2N3, CH3OCH2CHOHCH2N3, CH3OCH2CH(OCONHC4H9)CH2N3, N3CH2CH2O[CH2CH(CH2N3)O]6H, CH3CH2C[CH2(OCH2CH(CH2N3))2OCOCH3 ]3 N3CH2CH2OCONH(CH2)6NHCOOCH2CH2N3, (CH3)3CNHCOOCH2CH2N3, n-C4H9NDCOOCH2CH2N3, C6H5NHCOOCH2CH2N3, C4F9OCFCF3NDCOOCH2CH2N3, DOCH2CH2N3, [(CH3)3NCH2CH2N3]+ I