Classical theory of rotational excitation of diatomic molecules. Rotor–rotor coupling

摘要: Abstract The new concept of two momenta coupling is developed to treat the Coriolis and centrifugal one for rotors because they are important. A method classical canonical transformations applied coupling. theory scattering studied. obvious advantages angle–action variables describe angular internal motion Rotors have been employed. Canonical magnitudes dynamical generated by F 4 transformation function a partly coupled set fully one. Such generating was obtained extending Miller’s function. Relative molecules treated trajectories. theoretical model worked out study transport properties gases with rotational degrees freedom. structure resulting expressions under consideration shown be different in principle from other approaches. interplay between types influencing feasible determine. effect on energy transfer can studied framework such an approach. Previously, usage approximative treatment momentum imperative. designed incorporate recent improved formulas calculating coordinates their derivatives ensure most optimal calculation sequence.