Co(III), Ni(II), Zn(II) and Cd(II) complexes with 2-acetyl-2-thiazoline thiosemicarbazone: Synthesis, characterization, X-ray structures and antibacterial activity
作者： E. Viñuelas-Zahínos , F. Luna-Giles , P. Torres-García , M.C. Fernández-Calderón
DOI: 10.1016/J.EJMECH.2010.10.030
关键词:
摘要: Abstract The new ligand 2-acetyl-2-thiazoline thiosemicarbazone (HATtsc) and the complexes [Co(ATtsc)2]2[CoCl4]·2H2O (1), [Co(ATtsc)2]NO3·H2O (2), [Ni(HATtsc)2](NO3)2 (3), [ZnCl2(HATtsc)]·CH3CN (4), [{CdCl(HATtsc)}2(μ-Cl)2]·2H2O (5) [{Cd(NO3)(HATtsc)}2(μ-NO3)2] (6) were isolated characterized by a variety of physico-chemical techniques X-ray diffraction. structure HATtsc in 1 2 presented thiolate form while 3–6 thione was present, as it free ligand. In addition, we studied antibacterial activity 2–6 against some representative bacteria. Cd(II) more active Staphylococcus epidermidis, aureus, Enterococcus faecalis, Escherichia coli Bacillus subtilis than organic Conversely, compounds seemed to interfere cell separation B. subtilis.
elsevier.com
sci-hub.se 参考文章(43)
Djenana U. Miodragović, Dragana M. Mitić, Zoran M. Miodragović, Goran A. Bogdanović, Željko J. Vitnik, Maja D. Vitorović, Milanka Đ. Radulović, Branislav J. Nastasijević, Ivan O. Juranić, Katarina K. Anđelković, Syntheses, characterization and antimicrobial activity of the first complexes of Zn(II), Cd(II) and Co(II) with N-benzyloxycarbonylglycine: X-ray crystal structure of the polymeric Cd(II) complex Inorganica Chimica Acta. ,vol. 361, pp. 86- 94 ,(2008) , 10.1016/J.ICA.2007.06.041
Aysel Uğur, Bedrettin Mercimek, M. Ali Özler, Nurettin Şahin, Antimicrobial effects of bis(Δ2-2-imidazolinyl)-5,5′-dioxime and its mono- and tri-nuclear complexes Transition Metal Chemistry. ,vol. 25, pp. 421- 425 ,(2000) , 10.1023/A:1007064819271
J. J. Doyle, R. T. Marshall, W. H. Pfander, Effects of Cadmium on the Growth and Uptake of Microorganisms Applied and Environmental Microbiology. ,vol. 29, pp. 562- 564 ,(1975)
M D Mullen, D C Wolf, F G Ferris, T J Beveridge, C A Flemming, G W Bailey, Bacterial sorption of heavy metals. Applied and Environmental Microbiology. ,vol. 55, pp. 3143- 3149 ,(1989) , 10.1128/AEM.55.12.3143-3149.1989
Chun-nian Xia, Xi Wen, Wei-xiao Hu, Wei Zhou, Synthesis and anticancer activity of thiosemicarbazones Bioorganic & Medicinal Chemistry Letters. ,vol. 16, pp. 2213- 2218 ,(2006) , 10.1016/J.BMCL.2006.01.048
E. Viñuelas-Zahínos, F. Luna-Giles, P. Torres-García, A. Bernalte-García, Chloride-bridged Ni(II) complexes with ferromagnetic exchange interaction from thiazoline hydrazone derivative ligands Polyhedron. ,vol. 28, pp. 1362- 1368 ,(2009) , 10.1016/J.POLY.2009.02.030
N. H. Patel, H. M. Parekh, M. N. Patel, Synthesis, physicochemical characteristics, and biocidal activity of some transition metal mixed-ligand complexes with bidentate (NO and NN) Schiff bases Pharmaceutical Chemistry Journal. ,vol. 41, pp. 78- 81 ,(2007) , 10.1007/S11094-007-0017-2
M.T.H Tarafder, Khoo Teng Jin, Karen A Crouse, A.M Ali, B.M Yamin, H.-K Fun, Coordination chemistry and bioactivity of Ni2+, Cu2+, Cd2+ and Zn2+ complexes containing bidentate Schiff bases derived from S-benzyldithiocarbazate and the X-ray crystal structure of bis[S-benzyl-β-N-(5-methyl-2-furylmethylene)dithiocarbazato]cadmium(II) Polyhedron. ,vol. 21, pp. 2547- 2554 ,(2002) , 10.1016/S0277-5387(02)01188-9
Dhiman Kumar Sau, Ray J Butcher, Siddhartha Chaudhuri, Nityananda Saha, Synthesis and spectroscopic characterization of new cobalt(III) complexes with 5-methyl-3-formyl pyrazole 3-hexamethyleneiminyl thiosemicarbazone (HMPz3Hex): X-ray crystallographic identification of HMPz3Hex and [Co(MPz3Hex)2]Br · H2O with evidence for unusual rotation about the azomethine double bond of the ligand on complexation with cobalt(III) Polyhedron. ,vol. 23, pp. 5- 14 ,(2004) , 10.1016/J.POLY.2003.09.007
Tarlok S. Lobana, Rekha Sharma, Gagandeep Bawa, Sonia Khanna, Bonding and structure trends of thiosemicarbazone derivatives of metals—An overview Coordination Chemistry Reviews. ,vol. 253, pp. 977- 1055 ,(2009) , 10.1016/J.CCR.2008.07.004