Syntheses, characterization and antimicrobial activity of the first complexes of Zn(II), Cd(II) and Co(II) with N-benzyloxycarbonylglycine: X-ray crystal structure of the polymeric Cd(II) complex
作者： Djenana U. Miodragović , Dragana M. Mitić , Zoran M. Miodragović , Goran A. Bogdanović , Željko J. Vitnik
DOI: 10.1016/J.ICA.2007.06.041
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摘要: Abstract For the first time, complexes of Zn(II), Cd(II) and Co(II) (1–3) with N-benzyloxycarbonylglycine have been synthesized characterized. The adopt tetrahedral, pentagonal-bipyramidal octahedral geometry, respectively. structure polymeric cadmium complex was resolved by single crystal X-ray analysis. ion has a distorted coordination formed two water molecules N-benzyloxycarbonylglycinato ligands (N-Boc) coordinated in different fashions, one as bidentate second connecting three atoms. In rather complicated 2D supramolecular structure, phenyl rings interact mutually exclusively CH⋯π interactions. Investigation antimicrobial activity obtained revealed that ligand does not inhibit growth Candida albicans, whereas newly suppress this human fungal pathogen.
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sci-hub.se 参考文章(47)
Yu. I. Smolin, A. E. Lapshin, G. A. Pankova, Crystal Structure of [Co⋅6H2O][Co⋅4H2O⋅2Gly]⋅2SO4 Journal of Structural Chemistry. ,vol. 45, pp. 331- 334 ,(2004) , 10.1023/B:JORY.0000048887.48232.E1
Gautam R. Desiraju, Thomas Steiner, The Weak Hydrogen Bond: In Structural Chemistry and Biology ,(1999)
明 小谷, π-π Stacking assisted binding of aromatic amino acids by copper(ii)-aromatic diimine complexes. Effects of ring substituents on ternary complex stability Dalton Transactions. ,vol. 3, pp. 299- 307 ,(2007)
Nicole Niklas, Achim Zahl, Ralf Alsfasser, The structural mobility of zinc complexes with tetradentate tripodal ligands derived from the amino acids glycine and phenylalanine Dalton Transactions. pp. 778- 786 ,(2003) , 10.1039/B212049F
Adel Beghidja, Richard Welter, Pierre Rabu, Guillaume Rogez, Synthesis, structure and magnetic properties of a new family of chiral metal(II) citramalates Inorganica Chimica Acta. ,vol. 360, pp. 1111- 1120 ,(2007) , 10.1016/J.ICA.2006.08.034
Dj. U. Miodragović, S. M. Milosavljević, M. J. Malinar, M. B. Ćelap, N. Todorović, N. Juranić, Mixed cobalt(III) complexes with aromatic amino acids and diamine. Part IV. Influence of noncovalent intra-and interligand interactions on Rotamer population of the S-phenylalaninato and s-tyrosinato side groups in (1,2-diaminoethane)bis-(S-aminocarboxylato)cobalt(III) complexes Enantiomer. ,vol. 7, pp. 375- 382 ,(2002) , 10.1080/10242430215714
Noriko Chikaraishi Kasuga, Rumi Yamamoto, Akihiro Hara, Akifumi Amano, Kenji Nomiya, Molecular design, crystal structure, antimicrobial activity and reactivity of light-stable and water-soluble Ag–O bonding silver(I) complexes, dinuclear silver(I) N-acetylglycinate Inorganica Chimica Acta. ,vol. 359, pp. 4412- 4416 ,(2006) , 10.1016/J.ICA.2006.06.037
M. Nardelli, PARST95 – an update to PARST: a system of Fortran routines for calculating molecular structure parameters from the results of crystal structure analyses Journal of Applied Crystallography. ,vol. 28, pp. 659- 659 ,(1995) , 10.1107/S0021889895007138
Per E. M. Siegbahn, Robert H. Crabtree, Mechanism of C−H Activation by Diiron Methane Monooxygenases: Quantum Chemical Studies Journal of the American Chemical Society. ,vol. 119, pp. 3103- 3113 ,(1997) , 10.1021/JA963939M
Djenana U. Miodragović, Goran A. Bogdanović, Zoran M. Miodragović, Milanka Đ. Radulović, Sladjana B. Novaković, Goran N. Kaluđerović, Henryk Kozłowski, Interesting coordination abilities of antiulcer drug famotidine and antimicrobial activity of drug and its cobalt(III) complex. Journal of Inorganic Biochemistry. ,vol. 100, pp. 1568- 1574 ,(2006) , 10.1016/J.JINORGBIO.2006.05.009