Synthesis of the compounds [Re(CR)(CO)2(η5-C9H7)][BF4] (R = C6H4Me-4 or C6H3Me2-2,6) and the preparation of complexes with FeRe bonds

作者: Daniel Miguel , Uwe Steffan , F. Gordon , A. Stone

DOI: 10.1016/S0277-5387(00)81190-0

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摘要: Abstract The salts [Re(CR)CO) 2 (η 5 -C 9 H 7 )][BF 4 ] [R = C 6 Me-4 or 3 Me-2,6; η - indenyl] have been prepared and used to synthesize the dimetal compounds [FeRe(μ-CR)(μ-NO)(CO) )]. iron-rhenium species containing a bridging p tolylmethylidyne ligands react with [Fe (CO) [Ru(CO) (η-C )], respectively, yield trimetal ([FeMRe(μ -CC Me-4)(μ-CO)(μ-NO)(CO) )] (M Fe Ru).

参考文章(24)
Joseph M. O'Connor, Charles P. Casey, Ring-slippage chemistry of transition metal cyclopentadienyl and indenyl complexes Chemical Reviews. ,vol. 87, pp. 307- 318 ,(1987) , 10.1021/CR00078A002
Darjusch Mani, Heinrich Vahrenkamp, Rutheniumhaltige Heterometallcluster durch Aufbau und Metallaustausch Chemische Berichte. ,vol. 119, pp. 3639- 3648 ,(1986) , 10.1002/CBER.19861191212
Ernst Otto Fischer, Jürgen Karl Roman Wanner, Gerhard Müller, Jürgen Riede, Übergangsmetall‐Carben‐Komplexe, CXXXVI. Reaktionen kationischer Carbin‐Komplexe des Mangans mit Carbonylmetallaten Chemische Berichte. ,vol. 118, pp. 3311- 3319 ,(1985) , 10.1002/CBER.19851180830
F. G. A. Stone, Synthetic and structural studies on metal cluster compounds Pure and Applied Chemistry. ,vol. 58, pp. 529- 536 ,(1986) , 10.1351/PAC198658040529
Jesús Martin-Gil, Judith A. K. Howard, Rafael Navarro, F. Gordon A. Stone, Carbon monoxide transfer to a metal co-ordinated carbyne ligand: X-ray crystal structure of [Mn2{µ-C(CO)C6H4-Me-p}(CO)6(η-C5H5)]·0·5Et2O Journal of The Chemical Society, Chemical Communications. pp. 1168- 1169 ,(1979) , 10.1039/C39790001168