Melamine-assisted to fabricate pure α-Fe 2 O 3 polyhedron with high-index facet exposed as an effective photoelectrode

作者: Zhonghao Wang , Guojun Zou , Wei Wang , Zhicheng Tang , Yingpu Bi

DOI: 10.1016/J.JPOWSOUR.2017.01.035

关键词:

摘要: Introducing high-index facet into crystals is a promising way to provide additional catalytically active sites for boosting intrinsic activity. This work presents simple one-pot annealing fabricate highly photoactive pristine polyhedral α-Fe2O3 single crystal, using melamine as solvent and coordination agent. The HR-TEM results realized that the as-prepared sample was enclosed by {116} facet, which always not presented in traditional hydrothermal method. photoelectrochemical (PEC) measurements have been carried out showed polyhedron samples exhibited significantly enhancement photocurrent density, nearly 28 times higher than of prepared without under same conditions. Our may guide future designs crystal exposed metal oxides suggest paths further improvements allow technological development use.

参考文章(54)
Prasad Prakash Patel, Prashanth Jampani Hanumantha, Oleg I. Velikokhatnyi, Moni Kanchan Datta, Daeho Hong, Bharat Gattu, James A. Poston, Ayyakkannu Manivannan, Prashant N. Kumta, Nitrogen and cobalt co-doped zinc oxide nanowires – Viable photoanodes for hydrogen generation via photoelectrochemical water splitting ☆ Journal of Power Sources. ,vol. 299, pp. 11- 24 ,(2015) , 10.1016/J.JPOWSOUR.2015.08.027
Wangyin Wang, Zhiliang Wang, Qingjun Zhu, Guangye Han, Chunmei Ding, Jun Chen, Jian-Ren Shen, Can Li, Direct electron transfer from photosystem II to hematite in a hybrid photoelectrochemical cell Chemical Communications. ,vol. 51, pp. 16952- 16955 ,(2015) , 10.1039/C5CC06900A
Chong Wu Wang, Shuang Yang, Hai Bo Jiang, Huagui Yang, Chemical Vapor Deposition of FeOCl Nanosheet Arrays and Their Conversion to Porous α‐Fe2O3 Photoanodes for Photoelectrochemical Water Splitting Chemistry: A European Journal. ,vol. 21, pp. 18024- 18028 ,(2015) , 10.1002/CHEM.201503394
Michael J. Katz, Shannon C. Riha, Nak Cheon Jeong, Alex B.F. Martinson, Omar K. Farha, Joseph T. Hupp, Toward solar fuels: Water splitting with sunlight and “rust”? Coordination Chemistry Reviews. ,vol. 256, pp. 2521- 2529 ,(2012) , 10.1016/J.CCR.2012.06.017
Zhen-Huan Sheng, Lin Shao, Jing-Jing Chen, Wen-Jing Bao, Feng-Bin Wang, Xing-Hua Xia, Catalyst-Free Synthesis of Nitrogen-Doped Graphene via Thermal Annealing Graphite Oxide with Melamine and Its Excellent Electrocatalysis ACS Nano. ,vol. 5, pp. 4350- 4358 ,(2011) , 10.1021/NN103584T
Yongcai Qiu, Siu-Fung Leung, Qianpeng Zhang, Bo Hua, Qingfeng Lin, Zhanhua Wei, Kwong-Hoi Tsui, Yuegang Zhang, Shihe Yang, Zhiyong Fan, Efficient Photoelectrochemical Water Splitting with Ultrathin films of Hematite on Three-Dimensional Nanophotonic Structures Nano Letters. ,vol. 14, pp. 2123- 2129 ,(2014) , 10.1021/NL500359E
Jisheng Zhou, Huaihe Song, Xiaohong Chen, Linjie Zhi, Shubin Yang, Junping Huo, Wantai Yang, Carbon-Encapsulated Metal Oxide Hollow Nanoparticles and Metal Oxide Hollow Nanoparticles: A General Synthesis Strategy and Its Application to Lithium-Ion Batteries Chemistry of Materials. ,vol. 21, pp. 2935- 2940 ,(2009) , 10.1021/CM9006266
Kelley M. H. Young, Thomas W. Hamann, Enhanced photocatalytic water oxidation efficiency with Ni(OH)2 catalysts deposited on α-Fe2O3via ALD Chemical Communications. ,vol. 50, pp. 8727- 8730 ,(2014) , 10.1039/C4CC02598A