Direct Fabrication of Densely Packed Idiomorphic Li4Ti5O12 Crystal Layers on Substrates by Using a LiCl–NaCl Mixed Flux and Their Additive-Free Electrode Characteristics
作者： Nobuyuki Zettsu , Yusuke Mizuno , Hiroki Kojima , Kunio Yubuta , Takuya Sakaguchi
DOI: 10.1021/CG5009279
关键词:
摘要: Thin layers of densely packed idiomorphic Li4Ti5O12 crystals were prepared directly on a Pt substrate by using LiCl–NaCl mixed flux. The thin film colloidal anatase nanoparticles with an ∼30 nm diameter was fully converted into 100–200 having polyhedral shapes well-defined {111} faces during the evaporation-driven flux growth. Cross-sectional structure analysis revealed that interface between and seemed to be atomically bonded. Galvanometric charge discharge properties strongly supported our consideration formation. crystal layer exhibited large capacity close its theoretical value under 0.1C rate no assistance from additional electroconductive materials binders, meaning interfaces provide seamless transportation pathways. We also addressed formation mechanism accompanied experimental results in situ X-ray diffraction, t...
acs.org
elsevier.com
sci-hub.se 参考文章(41)
C. H. Chen, J. T. Vaughey, A. N. Jansen, D. W. Dees, A. J. Kahaian, T. Goacher, M. M. Thackeray, Studies of Mg-Substituted Li4−xMg x Ti5O12 Spinel Electrodes (0≤x≤1) for Lithium Batteries Journal of The Electrochemical Society. ,vol. 148, ,(2001) , 10.1149/1.1344523
J.-M. Tarascon, M. Armand, Issues and challenges facing rechargeable lithium batteries Nature. ,vol. 414, pp. 359- 367 ,(2001) , 10.1038/35104644
Eunae Kang, Yoon Seok Jung, Gi-Heon Kim, Jinyoung Chun, Ulrich Wiesner, Anne C. Dillon, Jin Kon Kim, Jinwoo Lee, Highly Improved Rate Capability for a Lithium-Ion Battery Nano-Li4Ti5O12 Negative Electrode via Carbon-Coated Mesoporous Uniform Pores with a Simple Self-Assembly Method Advanced Functional Materials. ,vol. 21, pp. 4349- 4357 ,(2011) , 10.1002/ADFM.201101123
D. Wang, N. Ding, X. H. Song, C. H. Chen, A simple gel route to synthesize nano-Li4Ti5O12 as a high-performance anode material for Li-ion batteries Journal of Materials Science. ,vol. 44, pp. 198- 203 ,(2009) , 10.1007/S10853-008-3104-1
Liang Zhao, Yong-Sheng Hu, Hong Li, Zhaoxiang Wang, Liquan Chen, Porous Li4Ti5O12 Coated with N‐Doped Carbon from Ionic Liquids for Li‐Ion Batteries Advanced Materials. ,vol. 23, pp. 1385- 1388 ,(2011) , 10.1002/ADMA.201003294
Erin M. Sorensen, Scott J. Barry, Ha-Kyun Jung, James M. Rondinelli, John T. Vaughey, Kenneth R. Poeppelmeier, Three-Dimensionally Ordered Macroporous Li4Ti5O12: Effect of Wall Structure on Electrochemical Properties Chemistry of Materials. ,vol. 18, pp. 482- 489 ,(2006) , 10.1021/CM052203Y
Yunyan Zhao, Shuping Pang, Chuanjian Zhang, Qinghua Zhang, Lin Gu, Xinhong Zhou, Guicun Li, Guanglei Cui, Nitridated mesoporous Li4Ti5O12 spheres for high-rate lithium-ion batteries anode material Journal of Solid State Electrochemistry. ,vol. 17, pp. 1479- 1485 ,(2013) , 10.1007/S10008-013-2026-2
Khalil Amine, Ilias Belharouak, Zonghai Chen, Taison Tran, Hiroyuki Yumoto, Naoki Ota, Seung-Taek Myung, Yang-Kook Sun, Nanostructured anode material for high-power battery system in electric vehicles. Advanced Materials. ,vol. 22, pp. 3052- 3057 ,(2010) , 10.1002/ADMA.201000441
M. Wagemaker, D. R. Simon, E. M. Kelder, J. Schoonman, C. Ringpfeil, U. Haake, D. Lützenkirchen-Hecht, R. Frahm, F. M. Mulder, A Kinetic Two‐Phase and Equilibrium Solid Solution in Spinel Li4+xTi5O12 Advanced Materials. ,vol. 18, pp. 3169- 3173 ,(2006) , 10.1002/ADMA.200601636
Wei Wang, Bo Jiang, Weiyi Xiong, Zhen Wang, Shuqiang Jiao, A nanoparticle Mg-doped Li4Ti5O12 for high rate lithium-ion batteries Electrochimica Acta. ,vol. 114, pp. 198- 204 ,(2013) , 10.1016/J.ELECTACTA.2013.10.035