Formation mechanism of tapering of crystals: a comparative study between potassium dihydrogen phosphate crystals and natural quartz crystals

作者: Taijing Lu , R.B. Yallee , C.K. Ong , I. Sunagawa

DOI: 10.1016/0022-0248(95)00043-7

关键词:

摘要: Abstract A comparative study on the tapering of natural quartz and potassium dihydrogen phosphate (KDP) crystals has been made. Both tapered KDP display similar surface microtopography featuring a large number tiny elongated growth islands striations regions. In addition to well accepted fact that trivalent metallic ions in aqueous solution can cause crystals, we find Pb 2+ same effect. This possibly originates from preferentially settled impurities embryonic crystallites along edges between two major faces.

参考文章(15)
一郎 砂川, Morphology and growth unit of crystals Terra Scientific Pub.. ,(1989)
F. Albert Cotton, Advanced Inorganic Chemistry ,(1999)
P. Bennema, O. Söhnel, Interfacial surface tension for crystallization and precipitation from aqueous solutions Journal of Crystal Growth. ,vol. 102, pp. 547- 556 ,(1990) , 10.1016/0022-0248(90)90412-E
G.M. Loiacono, J.J. Zola, G. Kostecky, The taper effect in KH2PO4 type crystals Journal of Crystal Growth. ,vol. 58, pp. 495- 499 ,(1982) , 10.1016/0022-0248(82)90134-8
Takatomo Sasaki, Atsushi Yokotani, Growth of large KDP crystals for laser fusion experiments Journal of Crystal Growth. ,vol. 99, pp. 820- 826 ,(1990) , 10.1016/S0022-0248(08)80033-4
Li Lian, Lu Taijing, Kazufumi Sakai, Tomoya Ogawa, In-situ observation of subcritical crystalline particles and their behavior on growth of KDP crystals from aqueous solution by light-scattering technique Journal of Materials Research. ,vol. 7, pp. 3275- 3279 ,(1992) , 10.1557/JMR.1992.3275
B. Dam, P. Bennema, W.J.P. Van Enckevort, The mechanism of tapering on KDP-type crystals Journal of Crystal Growth. ,vol. 74, pp. 118- 128 ,(1986) , 10.1016/0022-0248(86)90254-X
B. Dam, W.J.P. van Enckevort, In situ observation of surface phenomena on {100} and {101} potassium dihydrogen phosphate crystals Journal of Crystal Growth. ,vol. 69, pp. 306- 316 ,(1984) , 10.1016/0022-0248(84)90337-3
A.A. Chernov, L.N. Rashkovich, A.A. Mkrtchan, Solution growth kinetics and mechanism: Prismatic face of ADP Journal of Crystal Growth. ,vol. 74, pp. 101- 112 ,(1986) , 10.1016/0022-0248(86)90252-6
Osamu Shimomura, Masami Suzuki, The increase of temperature range in the region of supersaturation of KDP solution by addition of impurity Journal of Crystal Growth. ,vol. 98, pp. 850- 852 ,(1989) , 10.1016/0022-0248(89)90327-8