Rate-limiting one-electron transfer in the oxidation of NADH by polyoxometalates
作者： Bineta Keita , Khalid Essaadi , Louis Nadjo , Michel Desmadril
DOI: 10.1016/0009-2614(95)00331-W
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摘要: Abstract The kinetics of NADH oxidation by 3 Dawson-type mixed heteropolyanions were studied in buffered aqueous pH = 7 medium, the stopped flow technique and UV-visible spectroscopy. log k was a linear function E 0 first redox systems with slope 16.5 V −1 . results indicate that, present case, proceeds multistep mechanism involving initial rate-limiting one-electron transfer. An estimate value for NADH/NADH +· couple has been obtained.
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Mostefa. Abbessi, Roland. Contant, Rene. Thouvenot, Gilbert. Herve, Dawson type heteropolyanions. 1. Multinuclear (phosphorus-31, vanadium-51, tungsten-183) NMR structural investigations of octadeca(molybdotungstovanado)diphosphates .alpha.-1,2,3-[P2MM'2W15O62]n- (M, M' = Mo, V, W): syntheses of new related compounds Inorganic Chemistry. ,vol. 30, pp. 1695- 1702 ,(1991) , 10.1021/IC00008A006
Michael Thor Pope, Heteropoly and isopoly oxometalates Inorganic chemistry concepts. ,vol. 8, ,(1983) , 10.1007/978-3-662-12004-0
Polyoxometalates : from platonic solids to anti-retroviral activity Kluwer Academic Publishers. ,(1994) , 10.1007/978-94-011-0920-8
Lennart E. Eberson, Electron transfer reactions in organic chemistry ,(1987)
Mark. Vreeke, Ruben. Maidan, Adam. Heller, Hydrogen peroxide and .beta.-nicotinamide adenine dinucleotide sensing amperometric electrodes based on electrical connection of horseradish peroxidase redox centers to electrodes through a three-dimensional electron relaying polymer network Analytical Chemistry. ,vol. 64, pp. 3084- 3090 ,(1992) , 10.1021/AC00048A004
Brian W. Carlson, Larry L. Miller, Mechanism of the oxidation of NADH by quinones. Energetics of one-electron and hydride routes Journal of the American Chemical Society. ,vol. 107, pp. 479- 485 ,(1985) , 10.1021/JA00288A035
Werner G. Kuhr, Valerie L. Barrett, Michelle R. Gagnon, Phillip. Hopper, Paul. Pantano, Dehydrogenase-modified carbon-fiber microelectrodes for the measurement of neurotransmitter dynamics. 1. NADH voltammetry Analytical Chemistry. ,vol. 65, pp. 617- 622 ,(1993) , 10.1021/AC00053A022
Chihiro. Ueda, Daniel Chi-Sing. Tse, Theodore. Kuwana, Stability of catechol modified carbon electrodes for electrocatalysis of dihydronicotinamide adenine dinucleotide and ascorbic acid Analytical Chemistry. ,vol. 54, pp. 850- 856 ,(1982) , 10.1021/AC00243A003
In Sook Han. Lee, Drazen. Ostovic, Maurice. Kreevoy, Marcus theory of hydride transfer from an anionic reduced deazaflavin to NAD+ analogs Journal of the American Chemical Society. ,vol. 110, pp. 3989- 3993 ,(1988) , 10.1021/JA00220A043
Agnes Anne, Jacques Moiroux, Jean Michel Saveant, Formal hydride transfer from NADH analogs. 1-Benzyl-4-tert-butyl-1,4-dihydronicotinamide as a mechanistic probe Journal of the American Chemical Society. ,vol. 115, pp. 10224- 10230 ,(1993) , 10.1021/JA00075A043