Boron nitride nanotubes with reduced numbers of layers synthesized by arc discharge.

作者: A. Loiseau , F. Willaime , N. Demoncy , G. Hug , H. Pascard

DOI: 10.1103/PHYSREVLETT.76.4737

关键词:

摘要: A new route to the successful arc-discharge synthesis of pure boron nitride (BN) nanotubes is presented. The carbon-free plasma established between ${\mathrm{HfB}}_{2}$ electrodes in a nitrogen atmosphere. This technique leads formation BN with very few layers including single- and double-layer tubes. Electron-energy-loss spectroscopy yields B:N ratio approximately 1. Most tube ends are closed by flat perpendicular axis. closure triangular facet, resulting from three 120\ifmmode^\circ\else\textdegree\fi{} disclinations, proposed account for this specific shape.

参考文章(23)
Sumio Iijima, Helical microtubules of graphitic carbon Nature. ,vol. 354, pp. 56- 58 ,(1991) , 10.1038/354056A0
D. S. Bethune, C. H. Kiang, M. S. de Vries, G. Gorman, R. Savoy, J. Vazquez, R. Beyers, Cobalt-catalysed growth of carbon nanotubes with single-atomic-layer walls Nature. ,vol. 363, pp. 605- 607 ,(1993) , 10.1038/363605A0
C. Guerret-Piécourt, Y. Le Bouar, A. Lolseau, H. Pascard, Relation between metal electronic structure and morphology of metal compounds inside carbon nanotubes Nature. ,vol. 372, pp. 761- 765 ,(1994) , 10.1038/372761A0
O. Stephan, P. M. Ajayan, C. Colliex, Ph. Redlich, J. M. Lambert, P. Bernier, P. Lefin, Doping Graphitic and Carbon Nanotube Structures with Boron and Nitrogen Science. ,vol. 266, pp. 1683- 1685 ,(1994) , 10.1126/SCIENCE.266.5191.1683
Z. Weng-Sieh, K. Cherrey, Nasreen G. Chopra, X. Blase, Yoshiyuki Miyamoto, Angel Rubio, Marvin L. Cohen, Steven G. Louie, A. Zettl, R. Gronsky, Synthesis of B x C y N z nanotubules Physical Review B. ,vol. 51, pp. 11229- 11232 ,(1995) , 10.1103/PHYSREVB.51.11229
W. A. de Heer, A. Ch telain, D. Ugarte, A Carbon Nanotube Field-Emission Electron Source Science. ,vol. 270, pp. 1179- 1180 ,(1995) , 10.1126/SCIENCE.270.5239.1179
Sumio lijima, Toshinari Ichihashi, Yoshinori Ando, Pentagons, heptagons and negative curvature in graphite microtubule growth Nature. ,vol. 356, pp. 776- 778 ,(1992) , 10.1038/356776A0
Maohui Ge, Klaus Sattler, Observation of fullerene cones Chemical Physics Letters. ,vol. 220, pp. 192- 196 ,(1994) , 10.1016/0009-2614(94)00167-7
Sumio Iijima, P. M. Ajayan, T. Ichihashi, Growth model for carbon nanotubes. Physical Review Letters. ,vol. 69, pp. 3100- 3103 ,(1992) , 10.1103/PHYSREVLETT.69.3100
Z.G. Li, Paul J. Fagan, L. Liang, The three-dimensional of carbon nanotubes by high-resolution electron microscopy Chemical Physics Letters. ,vol. 207, pp. 148- 152 ,(1993) , 10.1016/0009-2614(93)87006-O