Trifluoroethoxy-Coated Phthalocyanine Catalyzes Perfluoroalkylation of Alkenes under Visible-Light Irradiation
作者： Kohei Matsuzaki , Tomoya Hiromura , Hideki Amii , Norio Shibata
DOI: 10.3390/MOLECULES22071130
关键词:
摘要: We disclose herein the perfluoroalkylation of alkenes catalyzed by trifluoroethoxy-coated zinc phthalocyanine under irradiation visible light. Perfluoroalkyl iodides were nicely incorporated into unsaturated substrates, including alkyne, to provide perfluoroalkyl and iodide adducts in moderate good yields. Trifluoromethylation is also possible trifluoromethyl same reaction conditions. The mechanistic study discussed.
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