Overview on microfluidic reactors in photocatalysis: Applications of graphene derivatives

作者: Ahmed Yusuf , Corrado Garlisi , Giovanni Palmisano , None

DOI: 10.1016/J.CATTOD.2018.05.041

关键词:

摘要: Abstract Microreactor technology represents one of the many methods for process intensification. Microreactors (MRs) truly inherit their tremendous properties from dimensions reaction environment and advantages cannot be overemphasized. They have remarkable heat mass transfer rates, short molecular diffusion distance, good laminar flow, better spatial illumination homogeneity as compared to conventional reactors due high surface-to-volume ratio. This review presents state-of-the-art information on applications this photocatalytic processes involving use graphene (GR) derivatives, either alone or in combination with inorganic semiconductor form nanocomposites. The latter are hybrid photocatalysts leveraging GR, which include electron mobility, excellent specific surface area, mechanical thermal properties. Because resulting photonic efficiency, enhanced interfacial area reduced electron-hole recombination, such catalysts increasingly studied tested photocatalysis. utilization GR derivatives drive advanced oxidation within MRs has, thus, potential afford a efficiency economic feasibility devices. However, studies application GR-derived semiconductors very limited at stage. It is hoped that overview will serve eye-opener researchers, create needed awareness more work still done, order able actualize explore potentials MRs. Full understanding would help going into details modelling challenging reactions gathering enough data can increase trigger eventual commercialization presented technologies.

参考文章(78)
Modeling of Process Intensification Published in <b>2007</b> in Weinheim by Wiley-VCH. ,(2007) , 10.1002/9783527610600
V. Russo, T. Kilpiö, J. Hernandez Carucci, M. Di Serio, T.O. Salmi, Modeling of microreactors for ethylene epoxidation and total oxidation Chemical Engineering Science. ,vol. 134, pp. 563- 571 ,(2015) , 10.1016/J.CES.2015.05.019
Jacob A. Moulijn, Michiel Makkee, Rob J. Berger, Catalyst testing in multiphase micro-packed-bed reactors; criterion for radial mass transport Catalysis Today. ,vol. 259, pp. 354- 359 ,(2016) , 10.1016/J.CATTOD.2015.05.025
Jean-Claude Charpentier, Mass-Transfer Rates in Gas-Liquid Absorbers and Reactors Advances in Chemical Engineering. ,vol. 11, pp. 1- 133 ,(1981) , 10.1016/S0065-2377(08)60025-3
Volker Hessel, Steffen Hardt, Holger Löwe, Chemical Micro Process Engineering Wiley. ,(2004) , 10.1002/3527603042
Serge Corbel, Guillaume Charles, Nidhal Becheikh, Thibault Roques-Carmes, Orfan Zahraa, Modelling and design of microchannel reactor for photocatalysis Virtual and Physical Prototyping. ,vol. 7, pp. 203- 209 ,(2012) , 10.1080/17452759.2012.708837
Dunpu Zhang, Wei Wang, Fengping Peng, Jiahui Kou, Yaru Ni, Chunhua Lu, Zhongzi Xu, None, A bio-inspired inner-motile photocatalyst film: a magnetically actuated artificial cilia photocatalyst. Nanoscale. ,vol. 6, pp. 5516- 5525 ,(2014) , 10.1039/C4NR00644E
Norbert Kockmann, Michael Gottsponer, Dominique M. Roberge, Scale-up concept of single-channel microreactors from process development to industrial production Chemical Engineering Journal. ,vol. 167, pp. 718- 726 ,(2011) , 10.1016/J.CEJ.2010.08.089
Sabrina A. Schmidt, Narendra Kumar, Arne Reinsdorf, Kari Eränen, Johan Wärnå, Dmitry Yu. Murzin, Tapio Salmi, Methyl chloride synthesis over Al2O3 catalyst coated microstructured reactor—Thermodynamics, kinetics and mass transfer Chemical Engineering Science. ,vol. 95, pp. 232- 245 ,(2013) , 10.1016/J.CES.2013.03.040