Hexaaquamanganese(II) bis[hydrotris(3-methyl-2-thioxo-1-imidazolyl) borate] Tetrahydrate: A Non-coordinating Borate Ligand with Manganese(II) Metal Ion
作者： S. Jayakumar , M. Nizam Mohideen , A. Kalilur Rahiman
DOI: 10.1080/15421406.2014.949844
关键词:
摘要: The metallation of a tripodal ligand, hydrotris(3-methyl-2-thioxo-1-imidazolyl)borate with manganese(II) salt gave an unusual title compound, [Mn(H2O)6](C12H16N6BS3)2.4H2O. presence soft donor atom in the borate moiety may be cause non-coordinating interaction metal ion. ion is coordinated six water molecules leads to distorted octahedral geometry. In crystal, cations, anions and uncoordinated are linked by intermolecular O‒H···O hydrogen bonds week O‒H···S C‒H···S interaction, generating three-dimensional network. thermal behavior compound was also investigated.
sci-hub.se 参考文章(15)
Raquel Garcia, António Paulo, Ângela Domingos, Isabel Santos, Kirstin Ortner, Roger Alberto, Re and Tc Complexes Containing B−H···M Agostic Interactions as Building Blocks for the Design of Radiopharmaceuticals Journal of the American Chemical Society. ,vol. 122, pp. 11240- 11241 ,(2000) , 10.1021/JA002652T
John Reglinski, Mark D. Spicer, Mark Garner, Alan R. Kennedy, Structural Consequences of the Use of Hard and Soft Tripodal Ligands during Metathesis Reactions: Synthesis of the [Bis(hydrotris(methimazolyl)borato]bismuth(III) [Bis(hydrotris(pyrazolyl)borato]sodiate Journal of the American Chemical Society. ,vol. 121, pp. 2317- 2318 ,(1999) , 10.1021/JA983637F
Iain Cassidy, Mark Garner, Alan R. Kennedy, Graeme B. S. Potts, John Reglinski, Paul A. Slavin, Mark D. Spicer, The Preparation and Structures of Group 12 (Zn, Cd, Hg) Complexes of the Soft Tripodal Ligand Hydrotris(methimazolyl)borate (Tm) European Journal of Inorganic Chemistry. ,vol. 2002, pp. 1235- 1239 ,(2002) , 10.1002/1099-0682(200205)2002:5<1235::AID-EJIC1235>3.0.CO;2-6
Hamsell M. Alvarez, Mariusz Krawiec, Bernadette T. Donovan-Merkert, Mouffouk Fouzi, Daniel Rabinovich, Modeling Nickel Hydrogenases: Synthesis and Structure of a Distorted Octahedral Complex with an Unprecedented [NiS4H2] Core Inorganic Chemistry. ,vol. 40, pp. 5736- 5737 ,(2001) , 10.1021/IC0155838
Clare Kimblin, Brian M. Bridgewater, David G. Churchill, Gerard Parkin, Mononuclear tris(2-mercapto-1-arylimidazolyl)hydroborato complexes of zinc, [TmAr]ZnX: structural evidence that a sulfur rich coordination environment promotes the formation of a tetrahedral alcohol complex in a synthetic analogue of LADH Chemical Communications. pp. 2301- 2302 ,(1999) , 10.1039/A906561J
Christopher A. Dodds, Alan R. Kennedy, John Reglinski, Mark D. Spicer, Pushing the frontiers of hard and soft scorpionate chemistry. Inorganic Chemistry. ,vol. 43, pp. 394- 395 ,(2004) , 10.1021/IC035167I
Swiatoslaw. Trofimenko, Boron-pyrazole chemistry. II. Poly(1-pyrazolyl)-borates Journal of the American Chemical Society. ,vol. 89, pp. 3170- 3177 ,(1967) , 10.1021/JA00989A017
L. J. Farrugia, ORTEP-3 for Windows - a version of ORTEP-III with a Graphical User Interface (GUI) Journal of Applied Crystallography. ,vol. 30, pp. 565- 565 ,(1997) , 10.1107/S0021889897003117
A. Altomare, G. Cascarano, C. Giacovazzo, A. Guagliardi, Completion and refinement of crystal structures with SIR92 Journal of Applied Crystallography. ,vol. 26, pp. 343- 350 ,(1993) , 10.1107/S0021889892010331
Mark Garner, John Reglinski, Iain Cassidy, Mark D. Spicer, Alan R. Kennedy, Hydrotris(methimazolyl)borate, a soft analogue of hydrotris(pyrazolyl)borate. Preparation and crystal structure of a novel zinc complex Chemical Communications. ,vol. 1996, pp. 1975- 1976 ,(1996) , 10.1039/CC9960001975