Solid-state field decoupler for off-column detection in capillary electrophoresis
作者： Wim T. Kok , Yuksel. Sahin
DOI: 10.1021/AC00066A017
关键词:
摘要: Palladium metal has been used to construct a robust and easy-to-handle field decoupler for capillary electrophoresis (CE) use with off-column detection. The tubular Pd electrode is applied as part of the wall system. capacity pass electrolytically generated hydrogen high enough accommodate electric currents usually found in CE. palladium imposes some demands on buffer be background electrolyte. Simple monovalent ions are allowed. With multivalent such phosphates, pH shifts during separation observed
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sci-hub.se 参考文章(17)
Y. Cheng, N. Dovichi, Subattomole amino acid analysis by capillary zone electrophoresis and laser-induced fluorescence Science. ,vol. 242, pp. 562- 564 ,(1988) , 10.1126/SCIENCE.3140381
Harold. Swerdlow, Jian Zhong. Zhang, Da Yong. Chen, Heather R. Harke, Ronda. Grey, Shaole. Wu, Norman J. Dovichi, Carl. Fuller, Three DNA sequencing methods using capillary gel electrophoresis and laser-induced fluorescence. Analytical Chemistry. ,vol. 63, pp. 2835- 2841 ,(1991) , 10.1021/AC00024A006
On the Dispersion of a Solute in a Fluid Flowing through a Tube Proceedings of The Royal Society A: Mathematical, Physical and Engineering Sciences. ,vol. 235, pp. 67- 77 ,(1956) , 10.1098/RSPA.1956.0065
David Perrett, Gordon Ross, Capillary electrophoresis: A powerful tool for biomedical analysis and research? Trends in Analytical Chemistry. ,vol. 11, pp. 156- 163 ,(1992) , 10.1016/0165-9936(92)87078-X
E. GASSMANN, J. E. KUO, R. N. ZARE, Electrokinetic separation of chiral compounds. Science. ,vol. 230, pp. 813- 814 ,(1985) , 10.1126/SCIENCE.230.4727.813
Ross A. Wallingford, Andrew G. Ewing, Separation of serotonin from catechols by capillary zone electrophoresis with electrochemical detection. Analytical Chemistry. ,vol. 61, pp. 98- 100 ,(1989) , 10.1021/AC00177A004
Sandra. Sloss, Andrew G. Ewing, Improved method for end-column amperometric detection for capillary electrophoresis Analytical Chemistry. ,vol. 65, pp. 577- 581 ,(1993) , 10.1021/AC00053A015
Ross A. Wallingford, Andrew G. Ewing, Amperometric detection of catechols in capillary zone electrophoresis with normal and micellar solutions. Analytical Chemistry. ,vol. 60, pp. 258- 263 ,(1988) , 10.1021/AC00154A015
Teresa M. Olefirowicz, Andrew G. Ewing, Capillary electrophoresis in 2 and 5 .mu.m diameter capillaries: application to cytoplasmic analysis Analytical Chemistry. ,vol. 62, pp. 1872- 1876 ,(1990) , 10.1021/AC00216A026
G.J.M. Bruin, G. Stegeman, A.C. Van Asten, X. Xu, J.C. Kraak, H. Poppe, Optimization and evaluation of the performance of arrangements for UV detection in high-resolution separations using fused-silica capillaries Journal of Chromatography A. ,vol. 559, pp. 163- 181 ,(1991) , 10.1016/0021-9673(91)80068-R