Reversible Reductive Dimerization of Diiron µ-Vinyl Complex via C–C Coupling: Characterization and Reactivity of the Intermediate Radical Species
作者： Adriano Boni , Tiziana Funaioli , Fabio Marchetti , Guido Pampaloni , Calogero Pinzino
DOI: 10.1021/OM200421A
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摘要: The diiron μ-vinyl complex [Fe2Cp2(CO)2(μ-CO){μ-η1:η2-CH═CH(Ph)}][BF4], [1][BF4], reacted with CoCp2 affording selectively the C–C coupling product [Fe2Cp2(CO)2(μ-CO){μ-CHCH(Ph)}]2, 2. cation [...
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