The first hydroxynitrile lyase catalysed cyanohydrin formation in ionic liquids
作者： Richard P. Gaisberger , Martin H. Fechter , Herfried Griengl
DOI: 10.1016/J.TETASY.2004.06.028
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摘要: Abstract Benzaldehyde, decanal, undecanal and dodecanal were reacted with hydrogen cyanide in a two phase solvent system aqueous buffer ionic liquids EMIM·BF 4 , PMIM·BF BMIM·BF the presence of hydroxynitrile lyases from Prunus amygdalus Hevea brasiliensis . When compared to use organic solvents as nonaqueous phase, reaction rate was significantly increased whereas enantioselectivity remained good.
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David Costes, Ernst Wehtje, Patrick Adlercreutz, Hydroxynitrile lyase-catalyzed synthesis of cyanohydrins in organic solvents: Parameters influencing activity and enantiospecificity Enzyme and Microbial Technology. ,vol. 25, pp. 384- 391 ,(1999) , 10.1016/S0141-0229(99)00055-1
Christian R. Noe, Max Knollm�ller, Helmut K�rner, Gerhard Steinbauer, Helmut Koberg, Peter G�rtner, Pheromone, 1. Mitt.: (+)-cis-Disparlure: Synthese und Feldtests Monatshefte Fur Chemie. ,vol. 122, pp. 101- 110 ,(1991) , 10.1007/BF00815171
Enzyme Catalysis in Organic Synthesis Wiley-VCH Verlag GmbH. ,(1995) , 10.1002/9783527618262
Peter Wasserscheid, Thomas Welton, Ionic Liquids in Synthesis ,(2002)
Carlos Baleizão, Bárbara Gigante, Hermenegildo Garcia, Avelino Corma, Ionic liquids as green solvents for the asymmetric synthesis of cyanohydrins catalysed by VO(salen) complexes Green Chemistry. ,vol. 4, pp. 272- 274 ,(2002) , 10.1039/B201497C
Adrianus M.C.H. van den Nieuwendijk, Erwin G.J.C. Warmerdam, Johannes Brussee, Arne van der Gen, AN ENANTIOSELECTIVE SYNTHESIS OF THE WILLIAMS GLYCINE TEMPLATE Tetrahedron-asymmetry. ,vol. 6, pp. 801- 806 ,(1995) , 10.1016/0957-4166(95)00076-2
Thomas Purkarthofer, Wolfgang Skranc, Hansjörg Weber, Herfried Griengl, Marcel Wubbolts, Gerald Scholz, Peter Pöchlauer, One-pot chemoenzymatic synthesis of protected cyanohydrins Tetrahedron. ,vol. 60, pp. 735- 739 ,(2004) , 10.1016/J.TET.2003.10.108
Seongsoon Park, Romas J Kazlauskas, Biocatalysis in ionic liquids – advantages beyond green technology Current Opinion in Biotechnology. ,vol. 14, pp. 432- 437 ,(2003) , 10.1016/S0958-1669(03)00100-9
Ernst Wehtje, Patrick Adlercreutz, Bo Mattiasson, Formation of C ? C bonds by mandelonitrile lyase in organic solvents Biotechnology and Bioengineering. ,vol. 36, pp. 39- 46 ,(1990) , 10.1002/BIT.260360106
Thomas Ziegler, Brigitte Hörsch, Franz Effenberger, Ein einfacher Zugang zu (R)-α-Hydroxycarbonsäuren und (R)- 1-Amino-2-alkoholen aus (R)-Cyanhydrinen Synthesis. ,vol. 1990, pp. 575- 578 ,(1990) , 10.1055/S-1990-26945