New EQCM, voltammetric and radiotracer evidences proving the role of Cu+ ions in the behavior of the Cu2+–Cu system
作者： Győző G Láng , Mária Ujvári , György Horányi , None
DOI: 10.1016/S0022-0728(02)00721-0
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摘要: Abstract Combined EQCM and voltammetric studies in conjunction with radiotracer adsorption investigations were carried out order to obtain direct information on the interfacial behavior of Cu 2+ –Cu system under equilibrium dynamic conditions aim clarifying role participation + ions formed by interaction cupric copper metal. The appearance accumulation solution phase is clearly demonstrated through experiments using labeled Cl − ions. formation bulk CuCl preceded a surface layer. Data obtained from combined allow us separate potential regimes where electrosorption, or ions, dissolution are predominant processes.
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