InGaN/GaN quantum dots as optical probes for the electric field at the GaN/electrolyte interface

作者: J. Teubert , S. Koslowski , S. Lippert , M. Schäfer , J. Wallys

DOI: 10.1063/1.4818624

关键词:

摘要: We investigated the electric-field dependence of photoluminescence-emission properties InGaN/GaN quantum dot multilayers in contact with an electrolyte. Controlled variations surface potential were achieved by application external electric fields using electrolytic Schottky and variation solution's pH value. Prior to characterization, a selective electrochemical passivation process was required suppress leakage currents. The luminescence is strongly affected variations, i.e., it increases exponentially cathodic bias acidic values. results cannot be explained modification intra-dot polarization induced via confined Stark effect but are attributed suppression/enhancement non-radiative recombination processes, mainly hole transfer into establish link between photoluminescence intensity magnitude at semiconductor/electrolyte interface.

参考文章(34)
A. Pakes, P. Skeldon, G. E. Thompson, J. W. Fraser, S. Moisa, G. I. Sproule, M. J. Graham, S. B. Newcomb, Anodic oxidation of gallium nitride Journal of Materials Science. ,vol. 38, pp. 343- 349 ,(2003) , 10.1023/A:1021125918526
Yong Xu, Martin A.A. Schoonen, The absolute energy positions of conduction and valence bands of selected semiconducting minerals American Mineralogist. ,vol. 85, pp. 543- 556 ,(2000) , 10.2138/AM-2000-0416
T. Rotter, D. Mistele, J. Stemmer, F. Fedler, J. Aderhold, J. Graul, V. Schwegler, C. Kirchner, M. Kamp, M. Heuken, Photoinduced oxide film formation on n-type GaN surfaces using alkaline solutions Applied Physics Letters. ,vol. 76, pp. 3923- 3925 ,(2000) , 10.1063/1.126822
J. I. Pankove, Electrolytic Etching of GaN Journal of The Electrochemical Society. ,vol. 119, pp. 1118- 1119 ,(1972) , 10.1149/1.2404410
V.I. Lobyshev, R.E. Shikhlinskaya, B.D. Ryzhikov, Experimental evidence for intrinsic luminescence of water Journal of Molecular Liquids. ,vol. 82, pp. 73- 81 ,(1999) , 10.1016/S0167-7322(99)00043-4
K Aryal, BN Pantha, J Li, JY Lin, HX Jiang, None, Hydrogen generation by solar water splitting using p-InGaN photoelectrochemical cells Applied Physics Letters. ,vol. 96, pp. 052110- ,(2010) , 10.1063/1.3304786
G. Steinhoff, M. Hermann, W. J. Schaff, L. F. Eastman, M. Stutzmann, M. Eickhoff, pH response of GaN surfaces and its application for pH-sensitive field-effect transistors Applied Physics Letters. ,vol. 83, pp. 177- 179 ,(2003) , 10.1063/1.1589188
Hye Seong Jung, Young Joon Hong, Yirui Li, Jeonghui Cho, Yong-Jin Kim, Gyu-Chul Yi, Photocatalysis using GaN nanowires. ACS Nano. ,vol. 2, pp. 637- 642 ,(2008) , 10.1021/NN700320Y
J. Renard, P. K. Kandaswamy, E. Monroy, B. Gayral, Suppression of nonradiative processes in long-lived polar GaN/AlN quantum dots Applied Physics Letters. ,vol. 95, pp. 131903- ,(2009) , 10.1063/1.3238311
Susanne Schäfer, Amelie H. R. Koch, Alda Cavallini, Martin Stutzmann, Ian D. Sharp, Charge Transfer across the n-Type GaN–Electrolyte Interface Journal of Physical Chemistry C. ,vol. 116, pp. 22281- 22286 ,(2012) , 10.1021/JP302000X